Unusual 31P chemical shielding tensors in terminal phosphido complexes containing a phosphorus-metal triple bond

Journal of the American Chemical Society

Volumn 118, Issue 43, 1996, Pages 10654-10655

  Wu, Gang ^a,b   Rovnyak, David ^a,b   Johnson, Marc J A ^b   Zanetti, Nadia C ^b   Musaev, Djamaladdin G ^c   Morokuma, Keiji ^c   Schrock, Richard R ^b   Griffin, Robert G ^a,b   Cummins, Christopher C ^b  

^a MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

^b MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

^c EMORY UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ORGANOPHOSPHORUS COMPOUND;

ARTICLE; DRUG STRUCTURE; MOLECULAR DYNAMICS; NUCLEAR MAGNETIC RESONANCE;

EID: 0029823201     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja960639w     Document Type: Article

References (29)

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29. There is an occupied MO of higher energy strongly localized on the N atoms, which is irrelevant to the present study. The P 3s lone pair MOs are lower in energy and need not be considered.