One-pot alkylidenediphosphorylation of nucleophiles

Synthesis

Volumn , Issue 6, 1996, Pages 731-735

  Grison, Claude ^a   Coutrot, Philippe ^a   Joliez, Stéphane ^a   Balas, Laurence ^a  

^a NANCY UNIVERSITÉ   (France)

Author keywords

alkylidene diphosphorylation; organophosphorus compounds; P C P bond formation

Indexed keywords

ORGANOPHOSPHORUS COMPOUND; PHOSPHONIC ACID DERIVATIVE;

ARTICLE; DRUG SYNTHESIS; INFRARED SPECTROPHOTOMETRY; NUCLEAR MAGNETIC RESONANCE; PHOSPHORYLATION; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 0029813320     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-1996-4283     Document Type: Article

References (29)

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27. 31P NMR spectra of the crude product 6aa-ap. Investigations are under way to understand the formation of these byproducts. They are supposed to result from the evolution of the product 6aa-ap and of the intermediate 5a in the reaction mixture when the nucleophilic attack on the P-Cl bond of 5 a fails or is too slow.
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