Evaluation of 1-(9-anthracenylmethyl) piperazine for the analysis of isocyanates in spray-painting operations

American Industrial Hygiene Association Journal

Volumn 57, Issue 10, 1996, Pages 914-917

  Rudzinski, Walter E ^a   Norman, Sam ^a   Dahlquist, Bruce ^b   Greebon, Kurt W ^c   Richardson, Andy ^c   Locke, K ^c   Thomas, Tom ^c  

^a Texas State University   (United States)

^b AIR FORCE RESEARCH LABORATORY   (United States)

^c Air Force Materiel Command   (United States)

Author keywords

1,6 hexamethylene diisocyanate (HDI); 1 (9 anthracenylmethyl)piperazine (MAP); spray painting

Indexed keywords

ISOCYANIC ACID DERIVATIVE; PIPERAZINE DERIVATIVE;

AIR SAMPLING; ARTICLE; CHEMICAL ANALYSIS; OCCUPATIONAL EXPOSURE; PAINT INDUSTRY; PAINTING;

EID: 0029797541     PISSN: 00028894     EISSN: None     Source Type: Journal    
DOI: 10.1080/15428119691014422     Document Type: Article

References (20)

1. Melcher, R.G.: Industrial hygiene. Anal. Chem. 55:40R-56R (1983).
2. Purnell, C.J. and R.F. Walker: Methods for the determination of atmospheric organic isocyanates. A review. Analyst 110:893-905 (1985).
3. Research and Development Laboratories: Analysis of Isocyanates in Spray Paint Operations, (RDL 34) by W.E. Rudzinski. Culver City, CA: Research and Development Laboratories, 1992.
4. Streicher, R.P., E.R. Kennedy, and C.D. Lorberau: Strategies for the simultaneous collection of vapours and aerosols with emphasis on isocyanate sampling. Analyst 119:89-97 (1994).
5. National Institute for Occupational Safety and Health (NIOSH): Isocyanates (Method 5521), by M.J. Seymour and A.W. Teass. In Manual of Analytical Methods, 3rd ed., vol. 2 (pub. no. 84-100). Washington, DC: U.S. Department of Health and Human Services, 1989.
6. Sango, C. and E. Zimerson: A new reagent for determination of isocyanates in working atmospheres by HPLC using UV or fluorescence detection. J. Liq. Chromatogr. 3:971 -990 (1980).
7. National Institute for Occupational Safety and Health (NIOSH): Isocyanates (Method: 5522), by R.J. Key-Schwartz and S.P Tucker. In Manual of Analytical Methods, 4th ed. Washington, DC: U.S. Department of Health and Human Services, 1993.
8. Streicher, R.P.: Method of Detecting Isocyanates, U.S. Patent No. 5,354,689. Oct. 11, 1994.
9. Streicher, R.P., J.E. Arnold, M.K. Ernst, and C.V. Cooper: Development of a novel derivatization reagent for the sampling and analysis of total isocyanate group in air and comparison of its performance with that of several established reagents. Am. Ind. Hyg. Assoc. J. 57:905-913 (1996).
10. Rudzinski, W.E., B. Dahlquist, S. Svejda, A. Richardson, et al: Sampling and analysis of isocyanates in spray-painting operations. Am. Ind. Hyg. Assoc. J. 56:284-289 (1995).
11. Janko, M., K. McCarthy, M. Fajer, and J. van Raalte: Occupational exposure to 1,6-hexamethylene diisocyanate-based polyisocyanates in the state of Oregon, 1980-1990. Am. Ind. Hyg. Assoc. J. 53:331-338 (1992).
12. American Conference of Governmental Industrial Hygienists (ACGIH): Threshhold Limit Values and Biological Exposure Indices for 1986-1987. Cincinnati, OH: ACGIH, 1987.
13. Hardy, H. and J. Devine: Use of organic isocyanates in industry. Some industrial hygiene aspects. Ann. Occup. Hyg. 22:421-427 (1979).
14. Silk, S.J. and H.L. Hardy: Control limits for isocyanates. Ann. Occup. Hyg. 27:333-339 (1983).
15. Belin, L., U. Hjortsberg, and U. Wass: Life-threatening pulmonary reaction to car paint containing a prepolymerized isocyanate. Scand. J. Work, Environ. Health 7:310-312 (1981).
16. Malo, J.L., G. Ouimet, A. Cartier, D. Levitz, et al.: Combined alveolitis and asthma due to hexamethylene diisocyanate (HDI), with demonstration of crossed respiratory and immunologic reactivities to diphenylmethane diisocyanate (MDI). J. Allergy Clin. Immunol. 72:413-419 (1983).
17. Nielsen, J., C. Sango, G. Winroth, T. Hallberg, et al: Systemic reactions associated with polyisocyanate exposure. Scand. J. Work, Environ. Health. 11:51-54 (1985).
18. Vandenplas, O., A. Cartier, J. LeSage, Y. Cloutier, et al: Prepolymers of hexamethylene diisocyanate as a cause of occupational asthma. J. Allergy Clin. Immunol. 91(4):850-861 (1993).
19. Tornling, G., R. Alexandersson, G. Hedenstierna, and N. Plato: Decreased lung function and exposure to diisocyanate (HDI) and (HDI-BT) in car repair painters; observations on re-examination 6 years after initial study. Am. J. Ind. Med. 17:299-300 (1990).
20. Cotton, T.: Statistics in Medicine. Boston, MA.: Little, Brown and Co., 1974.