Substitution of η2-dihydrogen by toluene and alkanes in IrXH2(H2)(PPr(i)3)2 complexes

Journal of the American Chemical Society

Volumn 118, Issue 36, 1996, Pages 8749-8750

  Lee, Do W ^a   Jensen, Craig M ^a  

^a UNIVERSITY OF HAWAII   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

IRIDIUM; METAL COMPLEX;

ARTICLE; COMPLEX FORMATION; MOLECULAR DYNAMICS; REACTION ANALYSIS;

EID: 0029793920     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9619014     Document Type: Article

References (19)

1. (a) Crabtree, R. H.; Lavin, M.; Bonneviot, L. J. Am. Chem. Soc. 1986, 108, 4032.
2. (b) Gonzalez, A.; Hoff, C. B. Inorg. Chem. 1989, 28, 4295.
3. (c) Zhang, K.; Gonzalez, A.; Hoff, C. B. J. Am. Chem. Soc. 1989, 111, 3627.
4. (d) Millar, J. M.; Kastrup, R. V.; Melchior, M. T.; Horvath, I. T.; Hoff, C. D.; Crabtree, R. H. J. Am. Chem. Soc. 1990, 112, 9643.
5. (e) Gusev, D. G.; Vymenits, A. B.; Bakhmutov, V. I. Inorg. Chem. 1992, 31, 1.
6. Le-Husebo, T.; Jensen, C. M. Inorg. Chem. 1993, 32, 3797.
7. Hauger, B. E.; Gusev, D. G.; Caulton, K. G. J. Am. Chem. Soc. 1994, 116, 208.
8. Mediati, M.; Tachibana, G. N.; Jensen, C. M. Inorg. Chem. 1992, 31, 1827.
9. 2 pressures ≤ 0.25 atm.
10. 1H NMR spectra of samples of the solvent containing an internal standard amount of THF which were equilibrated under 0.25 atm of hydrogen for 12 h in a constant temperature bath.
11. 3
12. Belli, J.; Jensen, C. M. Organometallics 1996, 15, 1532.
13. (a) Bonneau, R.; Kelly, J. M. J. Am. Chem. Soc. 1980, 102, 1220.
14. (b) Kelly, J. M.; Long, C.; Bonneau, R. J. Phys. Chem. 1983, 87, 3344.
15. (c) Simon, J. D.; Peters, S. Chem. Phys. Lett. 1983, 98, 53.
16. (d) Church, S. P; Grevels, F.-W.; Hermann, H.; Schaffner, K. Inorg. Chem. 1985, 24, 418.
17. (e) Creaven, B. S.; Dixon, A. J.; Kelley, J. M.; Long, C.; Poliakoff, M. Organometallics 1987, 6, 2600.
18. (f) Lian, T.; Bromberg, S. E.; Yang, H.; Proulx, G.; Bergman, R. G.; Harris, C. B. J. Am. Chem. Soc. 1996, 118, 3769.
19. Eckert, J.; Jensen, C. M.; Koetzle, T. F.; Le Husebo, T.; Nicol, J.; Wu, P. J. Am. Chem. Soc. 1995, 117, 7271.