Mossbauer study of Cys56Ser mutant 2Fe ferredoxin from Clostridium pasteurianum: Evidence for double exchange in an [Fe2S2]+ cluster

Journal of the American Chemical Society

Volumn 118, Issue 34, 1996, Pages 8168-8169

  Achim, Catalina ^a   Golinelli, Marie Pierre ^b   Bominaar, Emile L ^a   Meyer, Jacques ^b   Münck, Eckard ^a  

^a CARNEGIE MELLON UNIVERSITY   (United States)

^b CEA GRENOBLE   (France)

Author keywords

[No Author keywords available]

Indexed keywords

FERREDOXIN;

ARTICLE; CLOSTRIDIUM PASTEURIANUM; MOSSBAUER SPECTROSCOPY; MUTANT; PROTEIN STRUCTURE;

EID: 0029787939     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9617698     Document Type: Article

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15. 57Fe-containing synthetic medium.
16. 9/2 ranging from 0 to 8%. These effects are presently being studied.
17. -1.
18. 2]: ferredoxins are remarkably similar. We have used here the Rieske protein from Pseudomonas mendocina: Pikus, J. D.; Studts, J. M.; Achim, C.; Kauffmann, K. E.; Münck, E.; Steffan, R.; McClay, K.; Fox, B. G. Biochemistry 1996, 35, 9106.
19. z; the x- and y-components of the A tensors are undetermined.
20. 2+)]/2 = -9.1 MHz.
21. 2/χ.
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25. 7,15a
26. 9/2.
27. 9/2 mixture reflects a situation where the system is close to the crossing point of Figure 2B and the quantity J/B is distributed. Then, changes in the reorganization energy as a consequence of variation in the glycerol content could alter the composition of the mixture.
28. 3+ complex with octahedral N/O coordination at each site: Haase, W.; Fleischauer, P.; Werner, R.; Behlendorf, M.; Ensling, J.; Dutta, S. K.; Nag, K. J. Inorg. Biochem. 1995, 59, 285.
29. -1.