17O NMR study of chromium(VI) ions in water

Journal of the American Chemical Society

Volumn 118, Issue 34, 1996, Pages 7969-7980

  Brasch, Nicola E ^a   Buckingham, David A ^a   Evans, A Bram ^a   Clark, Charles R ^a  

^a UNIVERSITY OF OTAGO   (New Zealand)

Author keywords

[No Author keywords available]

Indexed keywords

CHROMIUM;

ARTICLE; MATHEMATICS; NUCLEAR MAGNETIC RESONANCE; TECHNIQUE; THEORY; WATER ANALYSIS;

EID: 0029785858     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja960843j     Document Type: Article

References (70)

1. Standeven, A. S.; Wetterhahn, K. E. J. Am. Coll. Toxicol. 1989, 8, 1275. Brauer, S. L.; Wetterhahn, K. E. J. Am. Chem. Soc. 1991, 113, 3001.
2. Standeven, A. S.; Wetterhahn, K. E. J. Am. Coll. Toxicol. 1989, 8, 1275. Brauer, S. L.; Wetterhahn, K. E. J. Am. Chem. Soc. 1991, 113, 3001.
3. Taube, H. Rec. Chem. Prog. 1956, 17, 25. Stranks, D. R.; Wilkins, R. G. Chem. Rev. 1957, 57, 743. Myers, O. E.; Prestwood. R. J. In Radioactivity Applied to Chemistry; Wahl, A. C., Bonner, N. A., Eds., Wiley: New York, 1951; Chapter 1. Gamsjäger, H.; Murmann, R. K. Adv. Inorg. Bioinorg. Mech. 1983, 2, 317.
4. Taube, H. Rec. Chem. Prog. 1956, 17, 25. Stranks, D. R.; Wilkins, R. G. Chem. Rev. 1957, 57, 743. Myers, O. E.; Prestwood. R. J. In Radioactivity Applied to Chemistry; Wahl, A. C., Bonner, N. A., Eds., Wiley: New York, 1951; Chapter 1. Gamsjäger, H.; Murmann, R. K. Adv. Inorg. Bioinorg. Mech. 1983, 2, 317.
5. Taube, H. Rec. Chem. Prog. 1956, 17, 25. Stranks, D. R.; Wilkins, R. G. Chem. Rev. 1957, 57, 743. Myers, O. E.; Prestwood. R. J. In Radioactivity Applied to Chemistry; Wahl, A. C., Bonner, N. A., Eds., Wiley: New York, 1951; Chapter 1. Gamsjäger, H.; Murmann, R. K. Adv. Inorg. Bioinorg. Mech. 1983, 2, 317.
6. Taube, H. Rec. Chem. Prog. 1956, 17, 25. Stranks, D. R.; Wilkins, R. G. Chem. Rev. 1957, 57, 743. Myers, O. E.; Prestwood. R. J. In Radioactivity Applied to Chemistry; Wahl, A. C., Bonner, N. A., Eds., Wiley: New York, 1951; Chapter 1. Gamsjäger, H.; Murmann, R. K. Adv. Inorg. Bioinorg. Mech. 1983, 2, 317.
7. Mills, G. A. J. Am. Chem. Soc. 1940, 62, 2833.
8. The elegance and significance of this early study has not. in our view, been properly recognized by subsequent investigators.
9. Baloga, M. R.; Earley, J. E. J. Phys. Chem. 1963, 67, 964.
10. Holyer, R. H.; Baldwin, H. W. Can. J. Chem. 1967, 45, 413.
11. Mak, S. Y. C. Ph. D. Thesis. University of Western Ontario, Canada, 1967.
12. Figgis, B. N.; Kidd, R. G.; Nyholm, R. S. Can. J. Chem. 1965, 43, 145.
13. Okumura, M.; Kitani, M.; Toyomi Y.; Okazaki N. Bull. Chem. Soc. Jpn. 1980, 53, 3143.
14. Anbar, M.; Gutman, S. Int. J. Appl. Radiat. Isot. 1959, 5, 23.
15. 2O following the establishment of chemical equilibrium but does not consider exchange prior to equilibrium or exchange into the various Cr(VI) species.
16. 2-), that chemical and isotopic exchange processes cannot be directly related; cf. ref 17.
17. Kintzinger, J.-P. In NMR 1981, 17, 1.
18. Figgis, B. N.; Kidd, R. G.; Nyholm, R. S. Proc. R. Soc. (London), 1962, A269, 469.
19. Kidd, R. G. Can. J. Chem. 1967, 45, 413.
20. McKay, H. A. C. Nature 1938, 142, 997. Harris, G. M. Trans. Faraday Soc. 1951, 47, 716. Frost, A. A.; Pearson, R. G. Kinetics and Mechanism, 2nd ed.; Wiley: New York, 1961: p 192. Moore, J. W.; Pearson, R. G. Kinetics and Mechanism, 3rd ed.; Wiley: New York, 1981; p 311. Logan, S. R. J. Chem. Educ. 1990, 67, 371.
21. McKay, H. A. C. Nature 1938, 142, 997. Harris, G. M. Trans. Faraday Soc. 1951, 47, 716. Frost, A. A.; Pearson, R. G. Kinetics and Mechanism, 2nd ed.; Wiley: New York, 1961: p 192. Moore, J. W.; Pearson, R. G. Kinetics and Mechanism, 3rd ed.; Wiley: New York, 1981; p 311. Logan, S. R. J. Chem. Educ. 1990, 67, 371.
22. McKay, H. A. C. Nature 1938, 142, 997. Harris, G. M. Trans. Faraday Soc. 1951, 47, 716. Frost, A. A.; Pearson, R. G. Kinetics and Mechanism, 2nd ed.; Wiley: New York, 1961: p 192. Moore, J. W.; Pearson, R. G. Kinetics and Mechanism, 3rd ed.; Wiley: New York, 1981; p 311. Logan, S. R. J. Chem. Educ. 1990, 67, 371.
23. McKay, H. A. C. Nature 1938, 142, 997. Harris, G. M. Trans. Faraday Soc. 1951, 47, 716. Frost, A. A.; Pearson, R. G. Kinetics and Mechanism, 2nd ed.; Wiley: New York, 1961: p 192. Moore, J. W.; Pearson, R. G. Kinetics and Mechanism, 3rd ed.; Wiley: New York, 1981; p 311. Logan, S. R. J. Chem. Educ. 1990, 67, 371.
24. McKay, H. A. C. Nature 1938, 142, 997. Harris, G. M. Trans. Faraday Soc. 1951, 47, 716. Frost, A. A.; Pearson, R. G. Kinetics and Mechanism, 2nd ed.; Wiley: New York, 1961: p 192. Moore, J. W.; Pearson, R. G. Kinetics and Mechanism, 3rd ed.; Wiley: New York, 1981; p 311. Logan, S. R. J. Chem. Educ. 1990, 67, 371.
25. Johnston, F. J. In Radiotracer Techniques and Applications; Evans, E. A., Muramatsu, M., Eds.; Marcel Dekker: New York, 1977; Vol. 1. p 405.
26. Eigen, M. Angew. Chem., Int. Ed. Engl. 1964, 3, 1.
27. Details of this analysis are available on request; they lead to the same rate equations as given here, but are somewhat more lengthy.
28. Mills, G. A.; Urey, H. C. J. Am. Chem. Soc. 1940, 62, 1019.
29. Details available on request.
30. Bernasconi, C. F. In Relaxation Kinetics: Academic Press: New York, 1976; pp 14-15.
31. That for Ẇ can be equated to the rate equation developed by Mills (cf. ref 3) following the establishment of chemical equilibrium.
32. 2O).
33. McKay, H. A. C. Nature 1938, 142, 997. Frost, A. A.; Pearson, R. G. Kinetics and Mechanism, 2nd ed.; Wiley: New York, 1961; p 192. Logan, S. R. J. Chem. Educ. 1990, 67, 371.
34. McKay, H. A. C. Nature 1938, 142, 997. Frost, A. A.; Pearson, R. G. Kinetics and Mechanism, 2nd ed.; Wiley: New York, 1961; p 192. Logan, S. R. J. Chem. Educ. 1990, 67, 371.
35. McKay, H. A. C. Nature 1938, 142, 997. Frost, A. A.; Pearson, R. G. Kinetics and Mechanism, 2nd ed.; Wiley: New York, 1961; p 192. Logan, S. R. J. Chem. Educ. 1990, 67, 371.
36. Neuss, J. D.; Rieman, W. J. Am. Chem. Soc. 1934, 56, 2238.
37. Davies, W. G.; Prue. J. E. Trans. Faraday Soc. 1955, 51, 1045.
38. Howard, J. R.; Nair, V. S. K.; Nancollas, G. H. Trans. Faraday Soc. 1958, 54, 1034.
39. Schwarzenbach, G.; Meir, J. J. Inorg. Nucl. Chem. 1958, 8, 302.
40. Tong, J. Y.-P.; King, E. L. J. Am. Chem. Soc. 1953, 75, 6180.
41. Sasaki, Y. Acta Chem. Scand. 1962, 16, 719.
42. Linge, H. G.; Jones, A. L. Aust. J. Chem. 1968, 21, 1445.
43. Palmer, D. A.; Wesolowski, D.; Mesmer, R. E. J. Soln. Chem. 1987. 16, 443.
44. Michel, G.; Machinoux, R. J. Raman, Spectrosc. 1983, 14, 22.
45. Michel, G.; Cahay, R. J. J. Raman Spectrosc. 1986, 17, 79.
46. Cieslak-Golonka M. Coord. Chem. Rev. 1991, 109, 223.
47. Brasch, N. E. Ph.D. Thesis, University of Olago, 1993.
48. Cieslak-Golonka, M.; Bartecki, A. Bull. Pol. Acad. Chem. Sci. 1978, 26, 53.
49. Miskowski, V.; Gray, H. B.; Ballhausen, C. K. Mol. Phys. 1974, 28, 729.
50. Jackson, J. A.; Taube, H. J. Phys. Chem. 1965, 69, 1844.
51. Brasch, N. E.; Buckingham, D. A.; Clark, C. R.; Rowan, A. E. Aust. J. Chem., in press.
52. Nonlinear least-squares analysis was used.
53. 4 shows four O atoms tetrahedrally disposed about Cr. Cf.: Siddiqi, K. S.; Siddiqi, M. R. H.; Khan, P.; Khan, S.; Zaidi, S. A. A. Synth. React. Inorg. Metal-Org. Chem. 1982, 12, 521.
54. Arnek, R.; Johansson, S. R. Acta Chem. Scand. 1972, 26, 2903.
55. Swinehart, J. H.; Castellan, G. W. Inorg. Chem. 1964, 3, 278. Swinehart, J. H. J. Chem. Educ. 1967, 44, 524.
56. Swinehart, J. H.; Castellan, G. W. Inorg. Chem. 1964, 3, 278. Swinehart, J. H. J. Chem. Educ. 1967, 44, 524.
57. Baharad, R.; Perlmutter-Hayman, B.; Wolff, M. A. J. Phys. Chem. 1969, 73, 4391.
58. Perlmutter-Hayman, B.; Wolff, M. A. J. Phys. Chem. 1967, 71, 1416.
59. Pladziewicz, J. R.; Espenson, J. H. Inorg. Chem. 1971, 10, 634.
60. Moore, P.; Kettle, S. F. A.; Wilkins, R. G. Inorg. Chem. 1966, 5, 220.
61. Moore, P.; Ducommun, Y.; Nichols, P. J.; Merbach, A. E. Helv, Chim. Acta 1983, 66, 2445.
62. Fischer, R.; Bye. J. Bull. Soc: Chim. Fr. 1964, 2920.
63. Brasch, N. E.; Buckingham, D. A.; Clark, C. R. Inorg. Chem. 1994, 33, 2683.
64. Brasch, N. E.; Buckingham, D. A.; Clark, C. R. Aust. J. Chem. 1994, 47, 2283.
65. Tong, J. Y.; Johnson, R. L. Inorg. Chem. 1966, 5, 1902.
66. Other extensive data (ref 37) showed that the rate was affected by specific cations rather than by the ionic strength.
67. This is presumably the explanation of Okumura's data (ref 9) also. which was attributed entirely to dimerization.
68. Grace, M. R.; Tregloan, P. A. Inorg. Chem. 1992, 31, 4524.
69. Muirhead, K. A.; Haight, G. P.; Beattie, J. J. Am. Chem. Soc. 1972, 94, 3006.
70. Winter, E. R. S.; Carlton, M.; Briscoe, H. V. A. J. Chem. Soc. 1940, 131.