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Samples were recovered from Pemex drill cores at depth intervals C1-N10 (1393 to 1394 m) and Y6-N19 (1377 to 1379.5 m) in the Chicxulub No 1 and Yucatan No. 6 wells, respectively, located ∼40 km apart near the center of the basin (6)
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-1 for 10 hours Analyses for 32 elements were obtained with the use of routine procedures of the Johnson Space Center INAA Laboratory [D. W. Mittlefehldt and M. M. Lindstrom, Geochim. Cosmochim. Acta 55, 77 (1991); D W Mittlefehldt, T.H See, F. Horz, Meteoritics 27, 361 (1992)].
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Subsplits of the melt rock powders, as well as those of the standards, were weighed to an accuracy of ± 0.02 mg and counted in the low-background Radiation Counting Laboratory at Johnson Space Center (32). In addition to Ir, abundances were obtained for Fe, Sc, Cr, Co, Ni, Sr, Ce, Eu, Tb, Hf, Th, and Zn. Because of uncertainties inherent in weighing small amounts of powder, particularly beyond the thirdgeneration splits (23), subsplit masses from the second generation onward were back-calculated by mass-balance normalization of the apparent Sc abundance for each subsplit to the mean Sc abundance of the five first-generation subsplits The subsplit masses were then used to convert all elemental masses into concentrations (32)
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note
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In a discussion of (25) and the apparent rarity of unalloyed Pt in nature, R. Rocchia et al. [Earth Planet Set. Lett. 99, 206 (1990)] suggest that "The-finding of pure Pt nuggets could well result from a contamination [A. Montanari, private communication, 1990]."
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El Goresy et al (31) state that ∼5% of metal grains within "Fremdlinge£ are Ir with subordinate Ru and note that their investigations did not disclose if such grains are indeed homogeneous alloys or aggregates of discrete PGE metals
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We thank D. McKay, D. Morrison, G. Ryder, A Treiman, and two anonymous referees for constructive reviews, D. Rueb for darkroom expertise, and D. Steinberg Schuraytz for editonal assistance. This work was made possible in part by grants from the National Aeronautics and Space Administration Planetary Geology and Geophysics Program and the National Science Foundation Continental Dynamics Program, and was completed while B.C.S. held a National Research Council Associateship at Johnson Space Center. Lunar and Planetary Institute contribution 884
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We thank D. McKay, D. Morrison, G. Ryder, A Treiman, and two anonymous referees for constructive reviews, D. Rueb for darkroom expertise, and D. Steinberg Schuraytz for editonal assistance. This work was made possible in part by grants from the National Aeronautics and Space Administration Planetary Geology and Geophysics Program and the National Science Foundation Continental Dynamics Program, and was completed while B.C.S. held a National Research Council Associateship at Johnson Space Center. Lunar and Planetary Institute contribution 884.
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