High-temperature Raman spectroscopy of silicate and aluminosilicate hydrous glasses: Implications for water speciation

Chemical Geology

Volumn 128, Issue 1-4, 1996, Pages 25-39

  Holtz, François ^a   Bény, Jean Michel ^a   Mysen, Bjorn O ^a,b   Pichavant, Michel ^a  

^a CNRS   (France)

^b GEOPHYSICAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALUMINOSILICATE; HYDROUS GLASS; RAMAN SPECTROSCOPY; SILICATE; SPECIATION; WATER;

EID: 0029768981     PISSN: 00092541     EISSN: None     Source Type: Journal    
DOI: 10.1016/0009-2541(95)00161-1     Document Type: Article

References (28)

1. Bartholomew, R.F., Butler, B.L., Hoover, H.L. and Wu, C.K., 1980. Infrared spectra of a water-containing glass. J. Am. Ceram. Soc., 63: 481-485.
2. 8 melts. Eur. J. Mineral., 7: 905-920.
3. Buback, M., Crerar, D.A. and Koplitz, L.V., 1987. Vibrational and electronic spectroscopy of hydrothermal systems. In: G.S. Ulmer and H.L. Barnes (Editors), Hydrothermal Experimental Techniques. Wiley, New York, N.Y., pp. 333-359.
4. Daniel, I., Gillet, P., Poc, B.T. and McMillan, P.F., 1995. In-situ high-temperature Raman spectroscopic studies of aluminosilicate liquids. Phys. Chem. Miner., 22: 74-86.
5. Farnan, I., Kohn, S.C. and Dupree, R., 1987. A study of the structural role of water in hydrous silica glass using cross-polarisation magic angle spinning NMR. Geochim. Cosmochim. Acta, 51: 2869-2873.
6. Frantz, J.D., Dubessy, J. and Mysen, B., 1993. An optical cell for Raman spectroscopic studies of supercritical fluids and its application to the study of water to 500°C and 2000 bar. Chem. Geol., 106: 9-26.
7. 2O solubility in haplogranitic melts: compositional, pressure, and temperature dependence. Am. Mineral., 80: 94-108.
8. Holtz F., Bény, J.M., Roux, J., Pichavant, M. and Behrens, H., 1995b. Water in silica-rich and alkali feldspar glasses: evidence for two contrasting incorporation mechanisms. Eos (Trans Am. Geophys. Union), 76: 648.
9. 2O in rhyolite melt to 1300°C. Am. Mineral., 78: 1324-1327.
10. Kiselev, A.V. and Lygin, V.I., 1975. Infrared Spectra of Surface Compounds. Wiley, New York, N.Y., 384 pp.
11. Kohn, S.C., Dupree, R. and Smith, M.E., 1989. Proton environments and hydrogen-bonding in hydrous silicate glasses from proton NMR. Nature (London), 337: 539-541.
12. Long, D.A., 1977. Raman Spectroscopy. McGraw-Hill, New York, N.Y.
13. 2 glass: a note on infrared and Raman spectra. Am. Mineral., 71: 772-778.
14. McMillan, P.F., Poe, B.T., Stanton, T.R. and Remmele R.L., 1993. A Raman spectroscopic study of H/D isotopically substituted hydrous aluminosilicate glasses. Phys. Chem. Miner., 19: 454-459.
15. 2 glass and supercooled liquid to 1950 K via high-temperature Raman spectroscopy. Geochim. Cosmochim. Acta, 58: 3653-3664.
16. 2 binary compositions in the temperature range 25-1475°C. Chem. Geol., 96: 321-332.
17. Mysen, B.O. and Frantz, J.D., 1994. Silicate melts at magmatic temperatures: in-situ structure determination to 1651°C and effect of temperature and bulk composition on the mixing behavior of structural units. Contrib. Mineral. Petrol., 117: 1-14.
18. +. Chem. Geol., 57: 303-331.
19. Mysen, B.O., Finger, L.W., Virgo, D. and Seifert, F.A., 1982. Curve-fitting of Raman spectra of silicate glasses. Am. Mineral., 67: 686-695.
20. Nakamoto, K., Margoshes, M. and Rundle, R.E., 1955. Stretching frequencies as a function of distances in hydrogen bonds. J. Am. Chem. Soc., 77: 6480-6486.
21. Nowak, M. and Behrens, H., 1995. The speciation of water in granitic glasses and melts determined by in situ near-infrared spectroscopy. Geochim. Cosmochim. Acta, 59: 3445-3450.
22. Roux, J., Holtz, F., Lefèvre, A. and Schulze, F., 1994. A reliable high-temperature setup for internally heated pressure vessels: applications to silicate melt studies. Am. Mineral., 79: 1145-1149.
23. 4. Am. Mineral., 67: 696-717.
24. Silver, L., Ihinger, P.D. and Stolper, E., 1990. The influence of bulk composition on the speciation of water in silicate glasses. Contrib. Mineral. Petrol., 104: 142-162.
25. Stolen, R.H. and Walrafen, G.E., 1976. Water and its relation to broken bond defects in fused silica. J. Chem. Phys., 64: 2623-2631.
26. Stolper, E., 1982a. The speciation of water in silicate melts. Geochim. Cosmochim. Acta, 46: 2609-2620.
27. Stolper, E., 1982b. Water in silicate glasses, an infrared spectroscopic study. Contrib. Mineral. Petrol., 81: 1-17.
28. Stolper, E., 1989. Temperature dependence of speciation of water in rhyolitic melts and glasses. Am. Mineral., 74: 1247-1257.