Dynamics of confined polymer melts: Topology and entanglement

Macromolecules

Volumn 29, Issue 3, 1996, Pages 1010-1013

  Shaffer, J Scott ^a  

^a UNIVERSITY OF SOUTHERN CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COMPUTER SIMULATION; DYNAMICS; MATHEMATICAL MODELS; RELAXATION PROCESSES; RHEOLOGY; SURFACES; TOPOLOGY;

CHAIN TOPOLOGY; CONFINED POLYMER MELTS; CONFINEMENT; ENTANGLEMENT; RELAXATION TIMES; SPECIAL BOND FLUCTUATION MODEL;

POLYMERS;

EID: 0029754167     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma951154f     Document Type: Article

References (35)

1. Bhushan, B.; Israelachvili, J. N.; Landman, U. Nature 1995, 374, 607.
2. Van Alsten, J.; Granick, S. Macromolecules 1990, 23, 4856.
3. Hu, H.-W.; Granick, S. Science 1992, 258, 1339.
4. Granick, S.; Hu, H.-W. Langmuir 1994, 10, 3857.
5. Peanasky, J.; Cai, L. L.; Granick, S.; Kessel, C. R. Langmuir 1994, 10, 3874.
6. Hu, H.-W.; Granick, S.; Schweizer, K. S. J. Non-Cryst. Solids 1994, 172-174, 721.
7. de Gennes, P.-G. J. Chem. Phys. 1971, 55, 572.
8. de Gennes, P.-G. Scaling Concepts in Polymer Physics; Cornell University Press: Ithaca, NY, 1979.
9. Doi, M.; Edwards, S. F. J. Chem. Soc., Faraday Trans. 1978, 74, 1789, 1802, 1818; 1978, 75, 38.
10. Doi, M.; Edwards, S. F. J. Chem. Soc., Faraday Trans. 1978, 74, 1789, 1802, 1818; 1978, 75, 38.
11. Doi, M.; Edwards, S. F. The Theory of Polymer Dynamics; Oxford University Press: New York, 1986.
12. Thompson, P. A.; Grest, G. S.; Robbins, M. O. Phys. Rev. Lett. 1992, 68, 3448.
13. Bitsanis, I. A.; Pan, C. J. Chem. Phys. 1993, 99, 5520.
14. Gupta, S.; Koopman, D. C.; Westermann-Clark, G. B.; Bitsanis, I. A. J. Chem. Phys. 1994, 100, 8444.
15. Rouse, P. E. J. Chem. Phys. 1953, 21, 1272.
16. Hess, W. Macromolecules 1988, 21, 2620.
17. Fixman, M. J. Chem. Phys. 1988, 89, 3892, 3912.
18. Schweizer, K. S. J. Chem. Phys. 1989, 91, 5802, 5822.
19. Di Marzio, E. A.; Rubin, R. J. J. Polym. Sci., Polym. Lett. Ed. 1978, 16, 457.
20. Fuller, G. G. J. Polym. Sci., Polym. Lett. Ed. 1983, 21, 151.
21. Atkinson, J.; Goh, C. J.; Phan-Thien, N. J. Chem. Phys. 1984, 80, 6305.
22. Spenley, N. A.; Gates, M. E. Macromolecules 1994, 27, 3850.
23. Subbotin, A.; Semenov, A.; Manias, E.; Hadziioannou, G.; ten Brinke, G. Macromolecules 1995, 28, 1511.
24. Subbotin, A.; Semenov, A.; Hadziioannou, G.; ten Brinke, G. Macromolecules 1995, 28, 3901.
25. Shaffer, J. S. J. Chem. Phys. 1994, 101, 4205.
26. Shaffer, J. S. J. Chem. Phys. 1995, 103, 761.
27. Carmesin, I.; Kremer, K. Macromolecules 1988, 21, 2819.
28. Deutsch, H.-P.; Binder, K. J. Chem. Phys. 1991, 94, 2294.
29. Paul, W.; Binder, K.; Heermann, D. W.; Kremer, K. J. Phys. (Paris) II 1991, 1, 37.
30. Binder, K. Physica A 1993, 200, 722.
31. Kremer, K.; Grest, G. S.; Carmesin, I. Phys. Rev. Lett. 1988, 61, 566.
32. Kremer, K.; Grest, G. S. J. Chem. Phys. 1990, 92, 5057.
33. de Gennes, P.-G. C. R. Acad. Sci. (Paris) 1987, 305, 1181.
34. Milchev, A.; Paul, W.; Binder, K. Macromol. Theory Simul. 1994, 3, 305.
35. Note that the data in Figure 4 represent relaxation times of the confined polymers normalized by the relaxation times in the bulk phase. In terms of unnormalized absolute magnitudes, the confined noncrossing chains still have larger relaxation times than the confined crossing chains.