Intrinsic barriers of the alternative modes of mesolytic fragmentations of C-S bonds

Journal of the American Chemical Society

Volumn 118, Issue 30, 1996, Pages 7235-7236

  Maslak, Przemyslaw ^a   Theroff, Jay ^a  

^a PENNSYLVANIA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

SULFIDE;

ARTICLE; DRUG DEGRADATION; TECHNIQUE; THERMODYNAMICS;

EID: 0029744634     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja960735x     Document Type: Article

References (44)

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23. See, for example: (a) Gan, H.; Leinhos, U.; Gould, I. R.; Whitten, D. G. J. Phys. Chem. 1995, 99, 3566. (b) Perrott, A. L.; Arnold, D. R. Can. J. Chem. 1992, 70, 272. (c) Norris, R. K.; Barker, S. D.; Neta, P. J. Am. Chem. Soc. 1984, 106, 3140. (d) Meot-Ner (Mautner), M.; Neta, P.; Norris, R. K.; Wilson, K. J. Phys. Chem. 1986, 90, 168. (e) Maslak, P.; Narvaez, J. N.; Vallombroso, T. M., Jr. J. Am. Chem. Soc. 1995, 117, 12373. (f) Masiak, P.; Chapman, W. H., Jr.; Vallombroso, T. M., Jr.; Watson, B. A. J. Am. Chem. Soc. 1995, 117, 12380.
24. See, for example: (a) Gan, H.; Leinhos, U.; Gould, I. R.; Whitten, D. G. J. Phys. Chem. 1995, 99, 3566. (b) Perrott, A. L.; Arnold, D. R. Can. J. Chem. 1992, 70, 272. (c) Norris, R. K.; Barker, S. D.; Neta, P. J. Am. Chem. Soc. 1984, 106, 3140. (d) Meot-Ner (Mautner), M.; Neta, P.; Norris, R. K.; Wilson, K. J. Phys. Chem. 1986, 90, 168. (e) Maslak, P.; Narvaez, J. N.; Vallombroso, T. M., Jr. J. Am. Chem. Soc. 1995, 117, 12373. (f) Masiak, P.; Chapman, W. H., Jr.; Vallombroso, T. M., Jr.; Watson, B. A. J. Am. Chem. Soc. 1995, 117, 12380.
25. See, for example: (a) Gan, H.; Leinhos, U.; Gould, I. R.; Whitten, D. G. J. Phys. Chem. 1995, 99, 3566. (b) Perrott, A. L.; Arnold, D. R. Can. J. Chem. 1992, 70, 272. (c) Norris, R. K.; Barker, S. D.; Neta, P. J. Am. Chem. Soc. 1984, 106, 3140. (d) Meot-Ner (Mautner), M.; Neta, P.; Norris, R. K.; Wilson, K. J. Phys. Chem. 1986, 90, 168. (e) Maslak, P.; Narvaez, J. N.; Vallombroso, T. M., Jr. J. Am. Chem. Soc. 1995, 117, 12373. (f) Masiak, P.; Chapman, W. H., Jr.; Vallombroso, T. M., Jr.; Watson, B. A. J. Am. Chem. Soc. 1995, 117, 12380.
26. See, for example: (a) Gan, H.; Leinhos, U.; Gould, I. R.; Whitten, D. G. J. Phys. Chem. 1995, 99, 3566. (b) Perrott, A. L.; Arnold, D. R. Can. J. Chem. 1992, 70, 272. (c) Norris, R. K.; Barker, S. D.; Neta, P. J. Am. Chem. Soc. 1984, 106, 3140. (d) Meot-Ner (Mautner), M.; Neta, P.; Norris, R. K.; Wilson, K. J. Phys. Chem. 1986, 90, 168. (e) Maslak, P.; Narvaez, J. N.; Vallombroso, T. M., Jr. J. Am. Chem. Soc. 1995, 117, 12373. (f) Masiak, P.; Chapman, W. H., Jr.; Vallombroso, T. M., Jr.; Watson, B. A. J. Am. Chem. Soc. 1995, 117, 12380.
27. See, for example: (a) Gan, H.; Leinhos, U.; Gould, I. R.; Whitten, D. G. J. Phys. Chem. 1995, 99, 3566. (b) Perrott, A. L.; Arnold, D. R. Can. J. Chem. 1992, 70, 272. (c) Norris, R. K.; Barker, S. D.; Neta, P. J. Am. Chem. Soc. 1984, 106, 3140. (d) Meot-Ner (Mautner), M.; Neta, P.; Norris, R. K.; Wilson, K. J. Phys. Chem. 1986, 90, 168. (e) Maslak, P.; Narvaez, J. N.; Vallombroso, T. M., Jr. J. Am. Chem. Soc. 1995, 117, 12373. (f) Masiak, P.; Chapman, W. H., Jr.; Vallombroso, T. M., Jr.; Watson, B. A. J. Am. Chem. Soc. 1995, 117, 12380.
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35. Although the absolute values of the thermodynamic estimates may be in error by 2-4 kcal/mol. the errors of the relative data are estimated to be less than 1 kcal/mol. The comparison of differences between the modes of cleavage is based on the relative quantities.
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