Kinetics of methyl halide production by reaction of DMSP with halide ion

Marine Chemistry

Volumn 52, Issue 2, 1996, Pages 147-155

  Hu, Zhongyao ^a   Moore, Robert M ^a  

^a DALHOUSIE UNIVERSITY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

HALOGENATED HYDROCARBON; KINETICS; METHYL HALIDE; THERMODYNAMICS;

EID: 0029730937     PISSN: 03044203     EISSN: None     Source Type: Journal    
DOI: 10.1016/0304-4203(95)00077-1     Document Type: Article

References (26)

1. Ackman, R.G., Tocher, C.S. and McLachlan, J., 1966. Occurrence of dimethyl-β-propiothetin in marine phytoplankton. J. Fish. Res. Bd. Can., 23: 357-364.
2. Brinckman, F.E., Olson, G.J. and Thayer, J.S., 1985. Biological mediation of marine metal cycles: the case of methyl iodide. In: A.C. Sigleo and A. Hattori (Editors), Marine and Estuarine Geochemistry, Ch. 16. Lewis, Chelsea, MI, USA.
3. Elliott, S. and Rowland, F.S., 1993. Nucleophilic substitution rates and solubilities for methyl halides in seawater. Geophys. Res. Lett., 20 (11): 1043-1046.
4. Goldberg, E.D., 1963. The ocean as a chemical system. In: M.N. Hill (Editor), The Sea. Interscience, New York, NY, pp. 3-25.
5. Grimsrud, E.P. and Miller, D.A., 1980. Non-linear responses of the electron capture detector to alkyl monochlorides. J. Chromatogr., 192: 117-125.
6. Hoyt, S.D and Rasmussen, R.A., 1985. Determining trace gases in air and seawater. In: A. Zirino (Editor), Mapping Strategies in Chemical Oceanography. Am. Chem. Soc., Washington, DC.
7. Keller, M.D., Bellows W.K. and Guillard, R.R.L., 1989. Dimethyl sulfide production in marine phytoplankton. In: E.S. Saltzman and W.J Cooper (Editors), Biogenic Sulfur in the Environment. Am. Chem. Soc. Symp. Ser., 393: 167-182.
8. Khalil, M.A.K., Rasmussen, R.A. and Gunawardena, R., 1993. Atmospheric methyl bromide: trends and global mass balance. J. Geophys. Res., 98(D2): 2887-2896.
9. Lide, D., 1991-1992. CRC Handbook of Chemistry and Physics, 72nd ed., pp. 5-2, 5-24, 5-25.
10. 3Br in the eastern Pacific Ocean. Science, 267: 1002-1004.
11. Lovelock, J.E., 1975. Natural halocarbons in the air and in the sea. Nature, 256: 193-194.
12. 3X production by kelps, Limnol. Oceanogr., 32(3): 709-715.
13. Manley, S.L. and Dastoor, M.N., 1988. Methyl iodide production by kelps and associated microbes. Mar. Biol., 98: 477-482.
14. McElroy, M.B., Salawitch, R.J., Wofsy, S.C. and Logan, J.A., 1986. Reductions of Antarctic ozone due to synergistic interactions of chlorine and bromine. Nature, 321: 759-762.
15. Mellouki, A., Talukdar, R.K., Schmoltner, A., Gierczak, T., Mills, M.J., Solomon, S. and Ravishankara, A.R., 1992. Atmospheric life time and ozone depletion potentials of methyl bromide and dibromomethane. Geophys. Res. Lett., 19: 2059-2062.
16. Moore, R.M. and Tokarczyk, R., 1992. Chloro-iodomethane in N. Atlantic waters: a potentially significant sources of iodine. Geophys. Res. Lett., 19(17): 1779-1782.
17. Singh, H.B. and Kanakidou, M., 1993. An investigation of atmospheric sources and sinks of methyl bromide. Geophys. Res. Lett., 20(2): 133-136.
18. Singh, H.B., Salas, L.J. and Stiles, R., 1983. Methyl halide in and over the eastern Pacific (40°N-32°S). J. Geophys. Res., 88: 3684-3690.
19. Solomon, S., 1990. Progress towards a quantitative understanding of Antarctic ozone depletion. Nature, 347: 347-354.
20. Solomon, S., Garcia, R.R. and Ravishankara, A.R., 1994. On the role of iodine in ozone depletion. J. Geophys. Res., 99(D10): 20491-20499.
21. 3Cl) in phytoplankton cultures. Limnol. Oceanogr., 40: 189-195.
22. Tait, V.K., Moore, R.M. and Tokarcyk, R., 1994. Measurements of methyl chloride in the north-west Atlantic. J. Geophys. Res., 99(4): 7821-7833.
23. Thurman, H.V., 1988. Introductory Oceanography, 5th ed. Merrill/Bell/Howell, 168 pp.
24. Turner, S.M., Malin, G. and Liss, P.S., 1989. Dimethyl sulphide and DMSP in Europe Coastal and shelf Waters. In: E.S. Saltzman and W.J. Cooper (Editors), Biogenic Sulfur in the Environment. Am. Chem. Soc. Symp. Ser., Washington, DC, Ch. 12.
25. White, R.H., 1982. Analysis of dimethyl sulfonium compounds in marine algae, J. Mar. Res., 40: 529-536.
26. Zafiriou, O.C., 1975. Reactions of methyl halides with seawater and marine aerosols. J. Mar. Res., 33: 75-81.