Coordination of Si in Na2O-SiO2-P2O5 glasses using Si K- And L-edge XANES

American Mineralogist

Volumn 81, Issue 1-2, 1996, Pages 111-118

  Li, Dien ^a,b   Bancroft, G M ^a   Fleet, M E ^a  

^a UNIVERSITY OF WESTERN ONTARIO   (Canada)

^b NATL INST OF MAT AND CHEM RES   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

GLASS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SILICA; SILICATES; SODIUM COMPOUNDS; SYNCHROTRON RADIATION; X RAY ABSORPTION; X RAY ABSORPTION NEAR EDGE STRUCTURE SPECTROSCOPY;

BULK COMPOSITIONS; EDGE FEATURES; EDGE SPECTRA; GLASS SYSTEMS; K-EDGE SPECTRA; REGRESSION EQUATION; SILICATE-PHOSPHATE GLASS; X-RAY ABSORPTION NEAR-EDGE STRUCTURE;

SILICON;

SILICATE GLASS; SILICON COORDINATION; XANES;

EID: 0029730695     PISSN: 0003004X     EISSN: None     Source Type: Journal    
DOI: 10.2138/am-1996-1-214     Document Type: Article

References (45)

1. Bancroft, G.M. (1992) New development in far UV, soft X-ray research at the Canadian Synchrotron Radiation Facility. Canadian Chemical News, 44, 15-22.
2. 5 molar ratio. Physics and Chemistry of Glasses, 26, 68-73.
3. 5 glasses. Journal of Non-Crystalline Solids, 102, 196-204.
4. 5 on the viscosity of heploganitic liquid. European Journal of Mineralogy, 5, 133-140.
5. Dupree, R., Holland, D., and Mortuza, M.G. (1987) Six-coordinated silicon in glasses. Nature, 328, 416-417.
6. Dupree, R., Holland, D., Mortuza, M.G., Collins, J.A., and Lockyer, M.W.G. (1989) Magic angle spinning NMR of alkali phospho-aluminosilicate glasses. Journal of Non-Crystalline Solids, 127, 111-119.
7. Finger, L.W., and Hazen, R.M. (1991) Crystal chemistry of six-coordinated silicon: A key to understanding the Earth's deep interior. Acta Crystallographica, B47, 561-580.
8. Fröba, M., Wong, J., Behrens, P., Sieger, P., Rowen, M., Tanaka, T., Rek, Z., and Felsche, J. (1995a) Correlation of multiple scattering features in XANES spectra of Al and Si K edges to the Al-O-Si bond angle in aluminosilicate sodalites: An empirical study. Physica B, 208 and 209, 65-67.
9. 66 soft X-ray monochromator. Physica B, 208 and 209, 555-556.
10. Gan, H., and Hess, P.C. (1992) Phosphate speciation in potassium aluminosilicate glasses. American Mineralogist, 77, 495-506.
11. 5 glasses. Geochimica et Cosmochimica Acta, 58, 4633-4647.
12. Hess, P.C. (1991) The role of high field strength cations in silicates melts. In Advances in Physical Geochemistry, 9, 153-191.
13. Ito, E., and Takahashi, T. (1987) Ultrahigh-pressure phase transformations and the constitution of the deep mantle. In High-Pressure Research in Mineral Physics, Geophysical Monograph, 39, 221-229.
14. Jeanloz, R. (1990) The nature of the Earth's core. Annual Review of the Earth and Planetary Sciences, 18, 357-386.
15. Klug, H., and Alexander, L.E. (1974) X-ray diffraction procedures: For polycrystalline and amorphous materials, 966 p. Wiley, New York.
16. Kushiro, I. (1975) On the nature of silicate melt and its significance in magma genesis: Regularities in the shift of the liquidus boundaries involving olivine, pyroxene, and silica minerals. American Journal of Science, 275, 411-431.
17. Lagarde, P., Flank, A.M., Tourillon, G., Liebermann, R.C., and Itie, J.P. (1992) X-ray absorption near edge structure of quartz: Application to the structure of densified silica. Journal de Physiques 1, 2, 1043-1050.
18. 5. American Mineralogist, 79, 785-788.
19. 2) polymorphs: The structural characterization of opal. American Mineralogist, 79, 622-632.
20. 5 glasses: A XANES study. Journal of Non-Crystalline Solids, 188, 181-189.
21. Li, Dien, Bancroft, G.M., Fleet, M.E., and Feng, X.H. (1995b) Silicon K-edge XANES spectra of silicate minerals. Physics and Chemistry of Minerals, 22, 115-122.
22. Liebau, F. (1985) Structural chemistry of silicates, 347 p. Springer-Verlag, Berlin.
23. Liu, L.G. (1975) Post-oxide phases of olivine and pyroxene and mineralogy of the mantle. Nature, 258, 510-512.
24. London, D. (1987) Internal differentiation of rare element pegmatites: Effect of boron, phosphorus and fluorine. Geochimica et Cosmochimica Acta, 51, 403-420.
25. 2O5 content of feld-spars from peraluminous granites, pegmatites, and rhyolites. American Mineralogist, 77, 126-145.
26. London, D., Černý, P., Loomis, J.L., and Pan, J.J. (1990) Phosphorus in alkali feldspars of rare-element granitic pegmatites. Canadian Mineralogist, 28, 771-786.
27. 2O). Contributions to Mineralogy and Petrology, 113, 450-465.
28. Miya, T., Nakahara, M., and Inagaki, N. (1983) Single-mode fiber fabrication techniques for large capacity transmission systems. Reviews in Electronic Communication Laboratory, 31, 310-320.
29. Mysen, B.O., Ryerson, F.J., and Virgo, D. (1981) The structural role of phosphorus in silicate melts. American Mineralogist, 66, 106-117.
30. Nelson, C, and Tallant, D.R. (1984) Raman studies of sodium silicate glasses with low phosphate contents. Physics and Chemistry of Glasses, 25, 31-38.
31. Okura, T., Inoue, H., and Kanazawa, T. (1990) Molecular orbital calculation of SiKα chemical shift due to coordination in silicates and silicophosphates. Spectrochimica Acta, 45B, 711-717.
32. Ryerson, F.J., and Hess, P.C. (1978) Implications of liquid-liquid distribution coefficients to mineral-liquid partitioning. Geochimica et Cosmochimica Acta, 42, 921-932.
33. 5 in silicate melts. Geochimica et Cosmochimica Acta, 44, 611-624.
34. 29Si MAS NMR method. Nippon Seramikkusu Kyokai Gakujutsu Ronbunshi, 96, 571-573.
35. 3. Journal of Non-Crystalline Solids, 45, 115-126.
36. 4-x: Models for solid-state analogs. Physical Review B, 48, 14989-15001.
37. 9. American Mineralogist, 68, 581-585.
38. Tyliszczak, T. (1992) BAN data analysis program.
39. 2. American Journal of Science, 279, 970-988.
40. Watson, E.B. (1976) Two liquid partition coefficients: Experimental data and geochemical implications. Contributions to Mineralogy and Petrology, 56, 119-134.
41. Weeding, T.L., De Jong, B.H.W.S., Veeman, W.S., and Aitken, B.G. (1985) Silicon coordination changes from 4-fold to 6-fold on devitrification of silicon phosphate glass. Nature, 318, 352-353.
42. Wong, J., and Angell, C.A. (1976) Glass structure by spectroscopy, 436 p. Marcel Dekker, New York.
43. 2O, on the melting temperatures of albite and granite. American Journal of Science, 262, 930-939.
44. Yang, B.X., Middleton, F.H., Olsson, B.G., Bancroft, G.M., Chen, J.M., Sham, T.K., Tan, K.H., and Wallace, J.D. (1992) The design and performance of a soft X-ray double crystal monochromator beamline at Aladdin. Nuclear Instruments and Methods in Physics Research, A316, 422-436.
45. Zachariasen, W.H. (1932) The atomic arrangement in glass. Journal of American Chemical Society, 54, 3841-3851.