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85033064935
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note
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Method A: a benzene solution (20 mL) containing thiol (2 mmol), AIBN (0.2 mmol) and the appropriate alkyne (5 mmol) was refluxed for 3h. Method B: a benzene solution (5 mL) of thiol (2 mmol) was added within 3 h with a syringe pump to a boiling benzene solution of AIBN (1 mmol) and the appropriate alkyne 5 mmol). An additional amounts of AIBN (0.5 mmol) was added after 2 h. The resulting solution was refluxed for further 60 min.
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