History of ancient copper smelting pollution during Roman and medieval times recorded in Greenland ice

Science

Volumn 272, Issue 5259, 1996, Pages 246-249

  Hong, Sungmin ^a   Candelone, Jean Pierre ^a,b   Patterson, Clair C ^c   Boutron, Claude F ^a,d  

^a LABORATOIRE DE GLACIOLOGIE ET GÉOPHYSIQUE DE L ENVIRONNEMENT   (France)

^b CURTIN UNIVERSITY   (Australia)

^c CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

^d UNIV GRENOBLE ALPES   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ATMOSPHERIC POLLUTION; COPPER SMELTING; ICE CORE; POLLUTION;

GREENLAND;

ROMAN;

EID: 0029663642     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.272.5259.246     Document Type: Article

References (28)

1. S. Hong, J. P. Candelone, C. C. Patterson, C. F. Bouton, Science 265, 1841 (1994).
2. I. Renberg, M. W. Persson, O. Emteryd, Nature 368, 323 (1994)
3. J. P. Candelone, S. Hong, C. I Pellone, C. F. Boutron, J. Geophys. Res. 100, 16605 (1995)
4. W. Dansgaard et al., Nature 364, 218 (1993)
5. J P Candelone, S. Hong, C. F Boutron, Anal. Chim. Acta 299, 9 (1994).
6. Substantial copper contamination was found in the outermost layer of the core sections. Concentrations then decreased in the second or third layers. Good plateaus of concentrations were obtained from the second or third layers for all but one of the investigated core sections; this indicates that the plateau concentration value represents the original concentration in the ice. The only exception was the section from a depth of 294 25 m (dated 1248 years ago). For this section, we used a value extrapolated from the radial profile, which showed a continuous decrease from the outside to the inside
7. Aluminum and sodium were measured by GFAAS with a precision of 10%. Aluminum is used to normalize copper concentrations in order to compensate for year-to-year changes in parameters such as atmospheric transport or precipitation rates
8. S. J. Johnsen, D. Dahl-Jensen, W Dansgaard, N. Gundestrup, Tellus 47B, 624 (1995).
9. J. O. Nriagu, Nature 338, 47 (1989).
10. Sulfate and ammonium were measured by ion chromatography with a precision of 10%
11. S. Hong, J. P Candelone, C. F. Boutron, in preparation.
12. J. O. Nriagu and J M. Pacyna, Nature 333, 134 (1988)
13. S. Hong, J. P. Candelone, M. Soutif, C. F. Boutron, in preparation
14. C. C Patterson, Am. Antiq. 36, 286 (1971).
15. A. S. Darling, in An Encyclopaedia of the History of Technology, I. McNeil, Ed (Routledge, London, 1990), pp. 47-145
16. R. F. Tylecote, A History of Metallurgy (Mid-County, London, 1976).
17. C. C. Patterson, Econ Hist Rev. 25 (2nd ser), 205 (1972).
18. J. F. Healy, Mining and Metallurgy in the Greek and Roman World (Thames and Hudson, London, 1988).
19. M Lombard, Les Métaux dans l'Ancien Monde du Ve au Xle siècle (Mouton, Paris, 1974).
20. N J G Pounds, An Historical Geography of Europe (Cambridge, London, 1990).
21. Archaeometallurgy Group, Beijing University of Iron and Steel Technology, A Brief History of Metallurgy in China (Science Press, Beijing, 1978).
22. J. Ch'en, Bull. Sch. Orient. Afr. Stud. 28, 613 (1965).
23. R F. Tylecote, The Early History of Metallurgy in Europe (Longman, London, 1987).
24. R J Forbes, in A History of Technology, Vol. II, C. Singer, E. J. Holmyard, A. R. Hall, T I. Williams, Eds. (Clarendon Press, Oxford, 1956), pp. 48-80.
25. J. O. Nriagu, in Copper in the Environment, J. O Nriagu, Ed. (Wiley, New York, 1979), pp. 43-75
26. W E Raate, in Pollution of the Arctic Atmosphere, W. T Sturges, Ed (Elsevier, London, 1991), pp. 13-42.
27. -1.
28. This work is a contribution of GRIP organized by the European Science Foundation We thank B. Stauffer and J P. Steffensen for their assistance in ice core selection; M. Soutif, R. J. Delmas, and C. Domergue for helpful discussions; and the national funding agencies and organizations in Belgium, Denmark, France, Germany, Iceland, Italy, Switzerland, and the United Kingdom, as well as the XII Directorate of the Commission of European Communities, for financial support. Supported by the French Ministry of the Environment (grants 92295 and 94074), the Institut National des Sciences de l'Univers, the University Joseph Fourier of Grenoble, and the Institut Universitaire de France.