Estimation of hydroxyl radical concentrations in the marine atmospheric boundary layer using a reactive atmospheric tracer

Journal of Atmospheric Chemistry

Volumn 25, Issue 1, 1996, Pages 97-113

  Cooper, David J ^a  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

Author keywords

Atmospheric tracer; Dimethylsulfide; Hydroxyl radical; Marine boundary layer; Sea air exchange

Indexed keywords

DIMETHYL SULFIDE; HYDROXYL RADICAL; TRACER;

AIR MONITORING; AIR POLLUTION; ARTICLE; BOUNDARY LAYER; GAS EXCHANGE; LIGHT; MARINE ENVIRONMENT;

AIR-SEA INTERACTION; AIR/SEA EXCHANGE; ATMOSPHERIC BOUNDARY LAYER; ATMOSPHERIC CHEMISTRY; ATMOSPHERIC TRACER; DIMETHYLSULPHIDE; HYDROXYL RADICAL; HYDROXYL RADICALS; MARINE BOUNDARY LAYER; TROPOSPHERE;

EID: 0029660658     PISSN: 01677764     EISSN: None     Source Type: Journal    
DOI: 10.1007/BF00053287     Document Type: Article

References (45)

1. Albrecht, B. A., Jensen, M. P., and Syrett, W. J., 1995: Marine boundary layer structure and fractional cloudiness, J. Geophys. Res. 100, 14209-14222.
2. Anderson, B. E., Gregory, G. L., Barrick, J. D. W., Collins, J. E., Sachse, G. W., Hudgins, C. H., Bradshaw, J. D., and Sandholm, S. T., 1993: Factors influencing dry season ozone distributions over the tropical south Atlantic, J. Geophys. Res. 98, 23491-23500.
3. Andreae, M. O. and Raemdonck, H., 1983: Dimethylsulfide in the surface ocean and the marine atmosphere: A global view, Science 221, 744-747.
4. Andreae, M. O., Ferek, R. O., Bermond, F., Byrd, K. P., Engstrom, R. T., Hardin, S., Houmere, P. D., LeMarrec, F., Raemdonck H., and Chatfield, R. B., 1985: Dimethyl sulfide in the marine atmosphere, J. Geophys. Res. 90, 12891-12900.
5. Armerding, W., Spiekermann, M., and Comes, F. J., 1994: OH multipass absorption - absolute and in-situ method for local monitoring of tropospheric hydroxyl radicals, J. Geophys. Res. 99, 1225-1239.
6. Barnes, I., Bastian, V., Becker, R. H., and Overath, R. D., 1991: Kinetic studies of the reactions of IO, BrO and ClO with DMS, Int. J. Chem. Kinet. 23, 579-591.
7. Bates, T. S., Cline, J. D., Gammon, R. H., and Kelly-Hansen, S. R., 1987: Regional and seasonal variations in the flux of oceanic dimethylsulfide to the atmosphere, J. Geophys. Res. 92, 2930-2938.
8. Chameides, W. L., Davis, D. D., Gregory, G. L., Sachse, G., and Torres, A. L., 1989: Ozone precursors and ozone photochemistry over eastern North Pacific during the spring of 1984 based on the NASA GTE CITE-1 Airborne Observations, J. Geophys. Res. 94, 9799-9808.
9. Chatfield, R. B. and Crutzen, P. J., 1990: Are there interactions of iodine and sulfur species in marine air photochemistry?, J. Geophys. Res. 95, 22319-22341.
10. Cooper, D. J. and Saltzman, E. S., 1991: Measurements of atmospheric dimethylsulfide and carbon disulfide in the western atlantic boundary layer, J. Atmos. Chem. 12, 153-168.
11. Cooper, D. J. and Saltzman, E. S., 1993: Measurements of atmospheric dimethylsulfide, hydrogen sulfide and carbon disulfide during GTE/CITE 3, J. Geophys. Res. 98, 23397-23409.
12. Crutzen, P., 1974: Photochemical reactions initiated by and influencing ozone in unpolluted tropospheric air, Tellus 26, 47-57.
13. Eisele, F. L., Mount, G. H., Fehsenfeld, F. C., Harder, J., Marovich, E., Parrish, D. D., Roberts, J., Trainer, M., and Tanner, D., 1994: Intercomparison of tropospheric OH and ancillary trace gas measurements at Fritz Peak Observatory, Colorado, J. Geophys. Res. 99, 18605-18626.
14. Eisele, F. L., and Tanner, D. J., 1991, Ion-assisted tropospheric OH measurement, J. Geophys. Res. 96, 9295.
15. Ferek, R. J., Chatfield R. B., and Andreae, M. O., 1986, Vertical distribution of dimethyl sulphide in the marine atmosphere, Nature 320, 514-516.
16. Finlayson-Pitts, B. J., Ezell, M. J., Jayaweera, T. M., Berko, H. N., and Lai, C. C., 1992: Kinetics of the reactions of OH with methyl chloroform and methane - implications for global tropospheric OH and the methane budget, Geophys. Res. Lett. 19, 1371-1374.
17. Hofzumahaus, A., Dorn, H. P., Callies, J., Platt, U., and Ehhalt, D. H., 1991: Tropospheric OH concentration measurements by laser long-path absorption-spectroscopy, Atmos. Environ. (A) 25, 2017-2022.
18. Hynes, A. J., Wine P. H., and Semmes, D. H., 1986: Kinetics and mechanism of OH reactions with organic Sulfides, J. Phys. Chem. 90, 4148-4156.
19. Keene, W. C., Jacob, D. J., Pszenny, A. A. P., Duce, R. A., Schultztokos, J. J., and Galloway, J. N., 1993: Aqueous-phase chemical processes in deliquescent sea-salt aerosols - A mechanism that couples the atmospheric cycles of S and sea-salt - Comment, J. Geophys. Res. 98, 9047-9049.
20. Keene, W. C., Jacob D. J., and Fan, S. M., 1996: Reactive chlorine - A potential sink for dimethyl-sulfide and hydrocarbons in the marine boundary layer, Atmos. Environ. 30(6), R1-R3.
21. Klick, S. and Abrahamsson, K., 1992: Biogenic volatile iodated hydrocarbons in the ocean, J. Geophys. Res. 97, 12683-12687.
22. Liss, P. S. and Slater, P. G., 1974: Flux of gases across the air-sea interface, Nature 247, 181-184.
23. Logan, J. A., Prather, M. J., Wofsy, S. C., and McElroy, M. B., 1981: Tropospheric chemistry: A global perspective, J. Geophys. Res. 86, 7210-7254.
24. Lovelock, J. E., Maggs, R. J., and Rasmussen, R. A., 1972: Atmospheric dimethylsulfide and the natural sulfur cycle, Nature 237, 452-453.
25. 14CO observations and their use for estimating carbon monoxide removal rates, J. Geophys. Res. 99, 22915-22922.
26. Mount, G. H., 1992: The measurement of tropospheric OH by long path length absorption, 1, instrumentation, J. Geophys. Res. 97, 2427-2444.
27. O'Brien, R. J. and Hard, T. M., 1993: Tropospheric hydroxyl radical: A challenging analyte, Advances in Chemistry 232, 323-371.
28. Peng, T.-H., Broecker, W. S., Mathieu G. G., and Li, Y.-H., 1979: Radon evasion rates in the Atlantic and Pacific Oceans as determined during the Geosecs Program, J. Geophys. Res. 84, 2471-2486.
29. Platt, U., Winer, A. M., Niermann, H. W., Atkinson, R., and Pitts, J. N., Jr., 1984: Measurement of nitrate radical concentrations in continental air, Environ. Sci. Technol. 18, 365.
30. 3) in the atmosphere, Fres. J. Anal. Chem. 340, 633-637.
31. Prinn, R., Cunnold, D., Simmonds, P., Alyea, F., Boldi, R., Crawford, A., Fraser, P., Gutzler, D., Hartley, D., Rosen, R., and Rasmussen, R., 1992: Global average concentration and trend for hydroxyl radicals deduced from ALE GAGE trichloroethane (methyl chloroform) data for 1978-1990, J. Geophys. Res. 97, 2445-2461.
32. Reifenhauser, W. and Heumann, K. G., 1992: Determinations of methyl-iodide in the antarctic atmosphere and the south Polar Sea, Atmos. Environ. (A) 26, 2905-2912.
33. Saltzman, E. S. and Cooper, D. J., 1988, Shipboard measurements of atmospheric dimethylsulfide and hydrogen sulfide in the Caribbean and Gulf of Mexico, J. Atmos. Chem. 6, 191-209.
34. Saltzman, E. S. and Cooper, D. J., 1989, Dimethylsulfide and hydrogen sulfide in marine air, in: E. S. Saltzman and W. J. Cooper (eds), Biogenic Sulfur in the Environment, ACS Symposium Series 393, American Chemical Society, Washington, D. C., pp. 330-351.
35. Saltzman, E. S., Cooper, D. J., Yvon, S. A., Andreae, M. O., Andreae, T. W., Bandy, A. R., Bates, T. S., Davis, D. D., Ferek, R. J., Johnson, J. E., Shipham, M. C., and Thornton, D. C., 1996: Diurnal variations in atmospheric sulfur gases over the western equatorial Atlantic Ocean, J. Geophys. Res., in press.
36. Sander, R. and Crutzen, P. J., 1996: Model study indicating halogen activation and ozone destruction in polluted air masses transported to the sea, J. Geophys. Res. 101, 9121-9138.
37. Shipham, M. C., Bachmeier, A. S., and Anderson, B. E., 1993: CITE 3 meteorological highlights, J. Geophys. Res. 98, 23305-23324.
38. Suhre, K. and Rosset, R., 1994: DMS oxidation and turbulent transport in the marine boundary layer - A numerical study, J. Atmos. Chem. 18, 379-395.
39. Tanner, D. J. and Eisele, F. L., 1995: Present OH measurement limits and associated uncertainties, J. Geophys. Res. 100, 2883-2892.
40. Thompson, A. M., Johnson, J. E., Torres, A. L., Bates, T. S., Kelly, K. C., Atlas, E., Greenberg, J. P., Donahue, N. M., Yvon, S. A., Saltzman, E. S., Heikes, B. G., Mosher, B. W., Shashkov A. A., and Yegorov, V. I., 1993: Ozone observations and a model of marine boundary-layer photochemistry during SAGA-3, J. Geophys. Res. 98, 16955-16968.
41. Toon, O. B., Kasting, J. F., Turco R. P., and Liu, M. S., 1987: The sulfur cycle in the marine atmosphere, J. Geophys. Res. 92, 943-963.
42. Winer, A. M., Atkinson R., and Pitts Jr., J. N., 1984: Gaseous nitrate radical: Possible nighttime atmospheric sink for biogenic organic compounds, Science 224, 156-159.
43. Yvon, S. A., Plane, J. M. C., Nien, C.-F., Cooper D. J., and Saltzman, E. S., 1996b: Interaction between nitrogen and sulfur cyles in the polluted marine boundary layer, J. Geophys. Res. 101, 1379-1386.
44. Yvon, S. A., Saltzman, E. S., Cooper, D. J., Bates, T. S., and Thompson, A. M., 1996a: Atmospheric sulfur cycling in the tropical Pacific marine boundary layer (12° S, 135° W): A comparison of field data and model results 1. Dimethylsulfide, J. Geophys. Res., in press.
45. Yvon, S. A., and Saltzman, E. S., 1996: Atmospheric sulfur cycling in the tropical Pacific marine boundary layer ( 12° S, 135° W): A comparison of field data and model results 2. Sulfur dioxide, J. Geophys. Res., in press.