Cooperative organization of inorganic-surfactant and biomimetic assemblies

Science

Volumn 267, Issue 5201, 1995, Pages 1138-1143

  Firouzi, A ^a   Kumar, D ^a   Bull, L M ^a   Besier, T ^a   Sieger, P ^a   Huo, Q ^a   Walker, S A ^a   Zasadzinski, J A ^a   Glinka, C ^b   Nicol, J ^b   Margolese, D ^a   Stucky, G D ^a   Chmelka, B F ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

1,2,4 TRIMETHYLBENZENE; BENZENE DERIVATIVE; CETRIMIDE; METHYLAMINE; SILICATE; SURFACE ACTIVE AGENTS; SURFACTANT; TRIMETHYLOXAMINE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; CRYSTALLIZATION; ELECTRON MICROSCOPY; FREEZE FRACTURE; MICELLE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PH; TEMPERATURE; THERMODYNAMICS; X RAY CRYSTALLOGRAPHY;

BENZENE DERIVATIVES; CETRIMONIUM COMPOUNDS; CRYSTALLIZATION; CRYSTALLOGRAPHY, X-RAY; FREEZE FRACTURING; HYDROGEN-ION CONCENTRATION; MAGNETIC RESONANCE SPECTROSCOPY; METHYLAMINES; MICELLES; MICROSCOPY, ELECTRON; MOLECULAR STRUCTURE; SILICATES; SUPPORT, NON-U.S. GOV'T; SUPPORT, U.S. GOV'T, NON-P.H.S.; SUPPORT, U.S. GOV'T, P.H.S.; SURFACE-ACTIVE AGENTS; TEMPERATURE; THERMODYNAMICS;

EID: 0029651205     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.7855591     Document Type: Article

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67. At higher temperatures, TMB is expelled from the organic region of the aggregates (8). This effectively decreases the hydrophobic volume of the chains, which in turn enhances the local curvature of the surface, leading to formation of a hexagonal SLC phase. In addition, reequilibration of the D4R silicate species at higher temperatures to produce smaller oligomeric units, such as monomer, dimer, and D3R species, may contribute to the observed phase transition. The reverse processes occur during cooling to reproduce the lamellar SLC mesophase.
68. We thank A. Oertli for assistance with deuteration of the surfactant and A. Schneider, S. Weigel, and L. Madsen for helpful discussions. This work was funded in part by the U.S. National Science Foundation (NSF) under the Materials Research Laboratory program (DMR-9123048) and under grant DMR-9222527. B.F.C. acknowledges support from the NSF Young Investigator Program, the Camille and Henry Dreyfus Foundation, and the David and Lucile Packard Foundation. J.A.Z. and S.A.W. acknowledge support from Office of Naval Research grant N00014-90-J-1551, NSF grant CTS-9319447, and NIH grant GM 47334. This work was presented in part at the 10th International Zeolite Conference, July 1994, Garmisch-Partenkirchen, Germany.