Application of the zeroth approximation of the DISQUAC model to cyclohexane + n-alkane mixtures using different combinatorial entropy terms

Fluid Phase Equilibria

Volumn 112, Issue 1, 1995, Pages 63-87

  Gonzalez, J A ^a   Garcia de la Fuente, I ^a   Cobos, J C ^a   Casanova, C ^a   Ait Kaci, A ^b  

^a UNIVERSITY OF VALLADOLID   (Spain)

^b UNIVERSITY OF SCIENCES AND TECHNOLOGY HOUARI BOUMEDIENE   (Algeria)

Author keywords

Application; Combinatorial; Excess functions; Hydrocarbon mixtures; Infinite dilution activity coefficients; Solid liquid equilibria; Theory

Indexed keywords

APPROXIMATION THEORY; AROMATIC HYDROCARBONS; BINARY MIXTURES; COMBINATORIAL MATHEMATICS; ENTHALPY; ENTROPY; GIBBS FREE ENERGY; MATHEMATICAL MODELS; SPECIFIC HEAT;

CYCLOHEXANE; DISQUAC GROUP CONTRIBUTION MODEL; FLORY-HUGGINS TERM; KIKIC EXPRESSION; MOLAR MASS FUNCTIONS; PATTERSON EFFECT; STAVERMANN-GUGGENHEIM EQUATION; ZEROTH APPROXIMATION;

PHASE EQUILIBRIA;

EID: 0029404703     PISSN: 03783812     EISSN: None     Source Type: Journal    
DOI: 10.1016/0378-3812(95)02783-B     Document Type: Article

References (69)

1. Statistical thermodynamics of liquid mixtures: a new expression for the Gibbs energy of partly or completely miscible systems
2. Excess enthalpies at 298.15 K of binary mixtures of cyclohexane with n-alkanes
3. Excess heat capacities of cyclohexane + some normal or branched alkanes
4. Solute liquid-gas activity and partition coefficients with mixtures of n-hexadecane and n-octadecane with n,n-dibutyl-2-ethylhexylamide solvents
5. Effect of a phase transition on the solubility of a solid
6. Order destruction and order creation in binary mixtures of non-electrolytes
7. 20) + cyclohexane, + benzene, + 1,2,3,4-tetrahydronaphthalene, or + tetrachloromethane
8. Solubility and vapour pressures in saturated solutions of high-molecular-weight hydrocarbons
9. 28)+heptane or cyclohexane
10. 20) + hexane, +3-methylpentane, +2,2-dimethylbutane, or + cyclohexane
11. 58
12. Isomer effects in mixtures of hydrocarbons: some experimental excess volumes and enthalpies
13. Low-temperature thermal data for the nine normal paraffin hydrocarbons from octane to hexadecane
14. The excess free energy of mixtures of cyclohexane and n-hexadecane
15. The excess free energy of mixtures of cyclohexane and n-dodecane
16. The excess Gibbs energy of mixtures of cyclohexane with n-eicosane and with two other n-alkanes A relation of congruence
17. Prediction of excess functions of some multicomponent organic mixtures of hydrocarbons with a group contribution model
18. A characterization of the aliphatic/hydroxyl interactions using a group contribution model (DISQUAC)
19. Characterization of the alkanol/alkanol contacts and prediction of excess functions of ternary systems of two n-alkan-1-ols and one n-alkane using DISQUAC
20. Estimation of DISQUAC interchange energy parameters for 1-alkanols + benzene, or toluene mixtures
21. E for ternary mixtures containing 1-alkanols and hydrocarbons
22. Solid-liquid equilibria using DISQUAC. Prediction for 1-alkanol + n-alkane mixtures
23. Solid-liquid phase diagrams of some binary systems containing cyclohexane, oxane or 1, 4-dioxane and normal alkanes
24. New predictive equation for the solubility of solid n-alkanes in organic solvents
25. Excess enthalpies of liquid alkane mixtures at pressures up to 500 bar. I. Experimental results. Ber. Bunsenges
26. Group contribution methods for liquid mixtures: a critical review
27. Thermodynamics of binary liquid organic mixtures
28. A comparative study of thermodynamic properties and molecular interactions in mono- and polychloroalkane + n-alkane or + cyclohexane mixtures
29. Thermodynamics of organic mixtures. A generalized quasichemical theory in terms of group surface interactions
30. Thermodynamics of binary mixtures containing oxaalkanes. Part 3. Monoethers, polyethers, acetals, orthoesters and cyclic monoethers + n-alkanes or + cyclohexane
31. The combinatorial part of the UNIFAC and UNIQUAC models
32. Influence of size and shape effects on the solubility of hydrocarbons: the role of the combinatorial entropy
33. Solubility of n-docosane in n-hexane and cyclohexane
34. Thermodynamic effects of orientational order in chain-molecule mixtures Part 1 Heats of mixing of globular and normal alkanes
35. Activity coefficients of cyclohexane mixtures
36. The thermodynamic properties of binary mixtures containing an octane. II. Excess Gibbs functions
37. 12)
38. 8) mixtures
39. Solute activity coefficients at infinite dilution and specific volumes measured by gas-liquid chromatography
40. 14 n-alkanes
41. Low-temperature thermal data for n-pentane, n-heptadecane and n-octadecane
42. A thermodynamic study of solute-solvent interactions using gas-liquid chromatography
43. 12)
44. Thermal data. XVII. The heat capacity, entropy, and free energy of formation of cyclohexane. A new method of heat transfer in low temperature calorimetry
45. p, T, x, y Data of benzene + n-hexane and cyclohexane + n-heptane systems
46. 36 range
47. Excess enthalpies from flow microcalorimetry I Experimental method and excess enthalpies for carbon tetrachloride + cyclohexane + benzene and + octamethylcyclotetrasiloxane and of n-hexane + cyclohexane
48. An isothermal high-pressure flow calorimeter. The excess enthalpy of (cyclohexane + n-hexane) at different pressures at 288.15, 198.15 and 313.15 K
49. E calculated from (vapor + liquid) and (solid + liquid) equilibria
50. Limiting activity coefficients of nonpolar and polar solutes in both volatile and nonvolatile solvents by gas-chromatographys
51. A comparative study of thermodynamic properties of n-alkane or + cyclohexane mixtures with aliphatic, linear or heterocyclic, molecules containing the same functional groups
52. Limiting activity coefficients from an improved differential boiling point technique
53. Calorimetric measurements of partial molar excess enthalpies at infinite dilution
54. Estimation of DISQUAC interchange energy parameters for n-alkylamine + n-alkane mixtures
55. Heats of mixing of normal paraffin hydrocarbons with cyclohexane Application of the quasi-lattice theory
56. Excess properties of liquid cyclohexane/hydrocarbon mixtures. II. Excess Gibbs energy determined from total vapour pressure data. Ber. Bunsenges
57. ∞ using gas-liquid chromatography. I. Results for the stationary phases n-octacosane, 1-docosanol, 10-nonadecanone, and 1-eicosene
58. Complex formation between carbon tetrachloride and aromatic hydrocarbons
59. The excess enthalpies of cyclohexane + n-dodecane and + n-nonane
60. 8 hydrocarbons in n-tetracosane and n-dotriacontane