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Volumn 28, Issue 2, 1995, Pages 656-657

Main-Chain Chiral Polymers from β-Citronellene via Tandem Diene Metathesis Cyclization/Ring-Opening Metathesis Polymerization

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; CONFORMATIONS; GEL PERMEATION CHROMATOGRAPHY; INITIATORS (CHEMICAL); ISOMERIZATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OPTICAL PROPERTIES; RING OPENING POLYMERIZATION; SYNTHESIS (CHEMICAL); TOLUENE;

EID: 0029218983     PISSN: 00249297     EISSN: 15205835     Source Type: Journal    
DOI: 10.1021/ma00106a037     Document Type: Article
Times cited : (28)

References (32)
  • 6
    • 0028462518 scopus 로고
    • Recent examples include the ring-opening metathesis polymerization of enantiomerically-enriched bicyclo[2.2.1]-heptene derivatives, see
    • Recent examples include the ring-opening metathesis polymerization of enantiomerically-enriched bicyclo[2.2.1]-heptene derivatives, see: Sunaga, T.; Ivin, K. J.; Hofmeister, G. E.; Oskam, J. H.; Schrock, R. R. Macromolecules 1994, 27, 4043-4050.
    • (1994) Macromolecules , vol.27 , pp. 4043-4050
    • Sunaga, T.1    Ivin, K.J.2    Hofmeister, G.E.3    Oskam, J.H.4    Schrock, R.R.5
  • 8
    • 0025723342 scopus 로고
    • This process is distinct from the stereoselective polymerization of chiral monomers in which stereogenic centers of the monomer that will ultimately reside in the side chains of the polymer control the stereoselectivity of the polymerization process, and hence, the diastereomeric ratios of the newly formed main-chain stereogenic centers. See
    • This process is distinct from the stereoselective polymerization of chiral monomers in which stereogenic centers of the monomer that will ultimately reside in the side chains of the polymer control the stereoselectivity of the polymerization process, and hence, the diastereomeric ratios of the newly formed main-chain stereogenic centers. See: Giardelli, F.; Altomare, A.; Carlini, C. Prog. Polym. Sci. 1991, 16, 259-277.
    • (1991) Prog. Polym. Sci. , vol.16 , pp. 259-277
    • Giardelli, F.1    Altomare, A.2    Carlini, C.3
  • 9
    • 0001420365 scopus 로고
    • For examples of conformational control by substituents, see and references cited therein
    • For examples of conformational control by substituents, see: Nakano, T.; Okamoto, Y.; Hatada, K. J. Am. Chem. Soc. 1992, 114, 1318-1329 and references cited therein.
    • (1992) J. Am. Chem. Soc. , vol.114 , pp. 1318-1329
    • Nakano, T.1    Okamoto, Y.2    Hatada, K.3
  • 11
    • 0027871953 scopus 로고
    • For a recent review, see
    • For a recent review, see: Breslow, D. S. Prog. Polym. Sci. 1993, 18, 1141-1195.
    • (1993) Prog. Polym. Sci. , vol.18 , pp. 1141-1195
    • Breslow, D.S.1
  • 22
    • 0000133757 scopus 로고
    • Addition of 1,2-dimethoxyethane (DME) might improve the yield by extending the longevity of the catalyst (see however, its presence complicates the subsequent isolation of 1 (bp 65 °C) in pure form
    • Addition of 1,2-dimethoxyethane (DME) might improve the yield by extending the longevity of the catalyst (see: Fox, H. H.; Schrock, R. R.; O'Dell, R. J. Am. Chem. Soc. 1994, 13, 635–639); however, its presence complicates the subsequent isolation of 1 (bp 65 °C) in pure form.
    • (1994) Am. Chem. Soc. , vol.13 , pp. 635-639
    • Fox, H.H.1    Schrock, R.R.2    O'Dell, R.J.3
  • 26
    • 0026941334 scopus 로고
    • More recently, it has been reported that an inseparable mixture of 3-MCP and 4-methylcyclopentene can be copolymerized via ROMP, see
    • More recently, it has been reported that an inseparable mixture of 3-MCP and 4-methylcyclopentene can be copolymerized via ROMP, see: Makovetsky, K. L.; Gorbacheva, L. I.; Ostrovskaya, I. Y.; Golberg, A. I.; Mikaya, A. I.; Zakharian, A. A.; Filatova, M. P. J. Mol. Cat. 1992, 76, 65-78.
    • (1992) J. Mol. Cat. , vol.76 , pp. 65-78
    • Makovetsky, K.L.1    Gorbacheva, L.I.2    Ostrovskaya, I.Y.3    Golberg, A.I.4    Mikaya, A.I.5    Zakharian, A.A.6    Filatova, M.P.7
  • 29
    • 0004113479 scopus 로고
    • For a discussion of living polymers and, in particular, the consequences of monomer/living polymer equilibria, see Chapman & Hall: New York
    • For a discussion of living polymers and, in particular, the consequences of monomer/living polymer equilibria, see: Szwarc, M.; Beylen, M. V. Ionic Polymerization and Living Polymers; Chapman & Hall: New York, 1993.
    • (1993) Ionic Polymerization and Living Polymers
    • Szwarc, M.1    Beylen, M.V.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.