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Volumn 36, Issue 37, 1995, Pages 6627-6630

An expedient enantioselective synthesis of N-t-Boc-Protected Phenylsarcosine.

Author keywords

[No Author keywords available]

Indexed keywords

AMINO ACID DERIVATIVE; SARCOSINE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; DRUG SYNTHESIS; ENANTIOMER;

EID: 0029114704 PISSN: 00404039 EISSN: None Source Type: Journal
DOI: 10.1016/00404-0399(50)1371-N Document Type: Article

Times cited : (30)

References (12)

2
- 84985577017
- Asymmetric deprotonations: enantioselective syntheses of 2-substituted tert-(butoxycarbonyl)pyrrolidines
- (1991) Journal of the American Chemical Society , vol.113 , pp. 9708-9710
- Kerrick, S.T.¹ Beak, P.J.²

3
- 33845469631
- (1984) Chem. Rev. , vol.84 , pp. 471-523
- Beak, P.¹ William, J.Z.²

5
- 85064446386
- Kinetic Resolution of β-StereogenicO-Alkyl Carbamates by (-)-Sparteine-Assisted Deprotonation. External versus Internal Chiral Induction.
- (1993) Synlett , pp. 726-728
- Haller, J.¹ Hense, T.² Hoppe, D.³

6
- 85024609841
- 1H NMR and GCMS. The enantiomeric excesses were determined by optical rotation, litt. [Truncated]

9
- 85022428184
- Asymmetric substitution: highly enantioselective substitutions induced at the carbanion of a racemic organolithium substrate by (-)-sparteine
- (1993) Journal of the American Chemical Society , vol.115 , pp. 2516-2518
- Beak, P.¹ Du, H.J.²

10
- 85024650237
- As suggested by a referee, another possible explanation for this result is that the purpose of preforming the (-)sparteine·s-BuLi complex is to force the chiral ligand to chelate an equilibrating enantiomeric mixture of 3 to form diastereomeric complexes. Therefore, the asymmetric induction could be the result of a kinetic resolution mechanism rather than an enantioselective deprotonation.

11
- 0001332338
- and references cited therein.
- (1989) J. Am. Chem. Soc. , vol.111 , pp. 4005-4008
- Kaufmann, E.¹ Sieber, S.² von Schleyer, P.R.³

* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.