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Volumn 36, Issue 21, 1995, Pages 3745-3748

PdCl2-Complexes containing phosphinoferrocenyloxazoline ligands. X-Ray crystal structure analysis and application to Grignard cross-coupling

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE DERIVATIVE;

EID: 0029077392     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4039(95)00583-X     Document Type: Article
Times cited : (60)

References (23)
  • 7
    • 85049751006 scopus 로고
    • Asymmetric Synthesis and Highly Diastereoselective ortho-Lithiation of Oxazolinylferrocenes
    • (1995) Synlett , pp. 79
    • Nishibayashi1    Uemura2
  • 8
    • 33748227479 scopus 로고
    • The phosphinoaryloxazolines, which are very effective ligands for asymmetric allylic substitutions, rely solely upon such a tetrahedral chiral centre, see:
    • (1993) Angew. Chem., Int. Ed. Engl. , vol.32 , pp. 566
    • von Matt1    Pfaltz2
  • 16
    • 84914018994 scopus 로고    scopus 로고
    • 2 solution and the Schlenk tube stored in the freezer overnight. The resulting crystals were filtered and washed with dry hexane to give 9 (0.075 g, 87%).
  • 18
  • 19
    • 0011555481 scopus 로고
    • 3, 360 MHz) methyl ester singlets at 3.63 and 3.71 ppm. In a separate experiment, coupling of commercial (S)-(+)-2-phenylpropionic acid with (S)-(+)-methyl mandelate gave an ester with a singlet at 3.63 ppm (corresponding to, R)-(+)-3b).
    • (1989) J. Organomet. Chem. , vol.370 , pp. 397
    • Baker1    Brown2    Cooley3    Hughes4    Taylor5
  • 20
    • 84914018993 scopus 로고    scopus 로고
    • 2 and R were 0.1115 and 0.0433 for all data [0.1112 and 0.0427 for 3301 with I〉2σ(I)]. The absolute configuration was confirmed by application of the chirality test using the Flack parameter in SHELXL-93. Atomic coordinates, bond lengths, angles and thermal parameters have been deposited at the Cambridge Crystallographic Data Centre.
  • 21
    • 84914018992 scopus 로고    scopus 로고
    • Chem-X, Chemical Design Ltd, Roundway House, Cromwell Park, Chipping Norton, Oxon, OX7 5SR, U.K.
  • 23


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.