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Volumn 36, Issue 12, 1995, Pages 2153-2156

IPy2BF4 is also a useful reagent for stereospecific iodine-silicon exchange in open chain trimethylsilylalkenes

Author keywords

[No Author keywords available]

Indexed keywords

SILANE DERIVATIVE;

EID: 0028938919     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4039(95)00199-M     Document Type: Article
Times cited : (22)

References (30)
  • 1
    • 85005706466 scopus 로고
    • Electrophilic Substitution of Organosilicon Compounds- Applications to Organic Synthesis
    • (1979) Synthesis , pp. 761
    • Chan1    Fleming2
  • 29
    • 84914009866 scopus 로고    scopus 로고
    • To account for the retention of configuration, TMS-group elimination is intended taking place by nucleophilic attack on silicon from the conformation where the silyl group stabilization of the β-carbenium ion competes well with the iodonium bridge in equilibrium (see reference 14 in this letter).
  • 30
    • 84914009865 scopus 로고    scopus 로고
    • A 54% ethereal solution, commercially available from Merck.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.