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Volumn 51, Issue 17, 1995, Pages 5011-5018

Rhodium-mediated insertion of CF3-substituted carbenoid into O-H: An efficient method for the synthesis of α-trifluoromethylated alkoxy- and aryloxyacetic acid derivatives

Author keywords

[No Author keywords available]

Indexed keywords

3,3,3 TRIFLUOROPROPIONIC ACID DERIVATIVE; ACETIC ACID DERIVATIVE; UNCLASSIFIED DRUG;

EID: 0028904369     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4020(95)98698-H     Document Type: Article
Times cited : (50)

References (34)
  • 16
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    • Transition-metal catalyzed decomposition of aliphatic diazo compounds — New results and applications in organic synthesis
    • (1987) Top. Curr. Chem. , vol.137 , pp. 75
    • Mass1
  • 25
    • 84982342361 scopus 로고
    • Eine neue Methode zur Darstellung α,β-ungesättiger Ketone. Zerfall der Diazoketone RCOCN2CH2R′
    • For example
    • (1957) Justus Liebigs Annalen der Chemie , vol.602 , pp. 199
    • Frazen1
  • 31
    • 0027978020 scopus 로고
    • Diastereoselectivity in the OH insertion reactions of rhodium carbenoids derived from phenyldiazoacetates of homochiral alcohols
    • (1994) Tetrahedron Letters , vol.35 , pp. 5949
    • Aller1    Cox2    Miller3    Moody4
  • 32
    • 84916505877 scopus 로고    scopus 로고
    • The use of a bulky, non-nucleophilic base was found to be mandatory for this transformation because use of other bases such as lithium diisopropylamide or potassium t-butoxide led mostly to complex products resulting from further nucleophilic attack by these bases on the relatively labile intermediate 4.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.