A simple, effective, new, palladium-catalyzed conversion of enol silanes to enones and enals

Tetrahedron Letters

Volumn 36, Issue 14, 1995, Pages 2423-2426

  Larock, Richard C ^a   Hightower, Timothy R ^a   Kraus, George A ^a   Hahn, Pat ^a   Zheng, Deye ^a  

^a IOWA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDE; KETONE;

ARTICLE; DRUG SYNTHESIS; METHODOLOGY; REACTION ANALYSIS;

EID: 0028899917     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4039(95)00306-W     Document Type: Article

References (45)

1. Dehydrierung von Ketonen mit Palladium(II)-Verbindungen
2. A Useful Preparation of Cyclopentenones
3. The Regioselective α,β-Dehydrogenation of Ketosteroids by Palladium(II) Chloride
4. Dehydrogenation of steroidal ketones using benzeneseleninic anhydride
5. Oxygen atom transfer from iodylbenzene to diphenyl diselenide - a convenient method for dehydrogenation of steroidal 3-ketones
6. Dehydrogenation of steroidal and triterpenoid ketones using benzeneseleninic anhydride
7. Synthesis ofα,β=Unsaturated Cyclic Ketones by Sensitized Photooxidation of Silyl Enol Ethers
8. On the antarafacial stereochemistry of the thermal [1,7]-sigmatropic hydrogen shift
9. Total synthesis of a highly oxygenated quassinoid, (.+-.)-klaineanone
10. A Simple Synthesis of Carvone Using Silyl Enol Ethers
11. Intramolecular 1,3-diyl trapping reactions. Total synthesis of (.+-.)-hypnophilin and (.+-.)-coriolin. Formation of the trans-fused bicyclo[3.3.0]octane ring system
12. Enone formation from allyl .BETA.-keto esters, alkenyl allyl carbonates, silyl enol ethers, and enol acetates by the phosphine-free palladium catalyst.
13. Catalytic dehydrosilylation of 1-trimethylsilyloxycyclopent-1-ene into cyclopent-2-enone with oxygen over palladium supported on silica
14. A Bridgehead Carbocation Fragmentation Leading to the Taxane AB Ring System