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Volumn 6, Issue 11, 1995, Pages 2829-2840

Synthesis and investigation of a hindered, chiral, bicyclic guanidine

Author keywords

[No Author keywords available]

Indexed keywords

GUANIDINE DERIVATIVE; PYRIMIDINE DERIVATIVE;

ARTICLE; CHIRALITY; DRUG SYNTHESIS; NUCLEAR MAGNETIC RESONANCE; PRIORITY JOURNAL; REACTION ANALYSIS;

EID: 0028864068 PISSN: 09574166 EISSN: 1362511X Source Type: Journal
DOI: 10.1016/0957-4166(95)00374-X Document Type: Article

Times cited : (71)

References (34)

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2
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7
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- Synthesis and self association of 4,7-diamino-2,9-dimethyl-5,6,11a-triaza-6,11,11a,12-tetrahydronaphthacene derivatives as dibenzoguanidine receptors for oxoanion recognition
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9
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10
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11
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13
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15
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16
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18
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- Basic character of rare earth metal alkoxides. Utilization in catalytic carbon-carbon bond-forming reactions and catalytic asymmetric nitroaldol reactions
- Since the inception of the present work, a highly effective enantioselective catalytic variant of the nitroaldol reaction, employing chiral lanthanide complexes, has been reported by Shibasaki and co-workers. This group has also demonstrated the value of such methodology in the synthesis of enantiomerically pure β-amino alcohols. See e.g.:
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- Sasai¹ Suzuki² Arai³ Arai⁴ Shibasaki⁵

21
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22
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- Various chiral amines have been employed again with moderate success, for enantioselective catalysis of conjugate additions of nitroalkanes. See e.g., University of Groningen
- (1992) Ph.D. thesis
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23
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26
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- Preliminary communication:
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28
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- Boyle, P.H.; Davis, A.P.; Dempsey, K.J.; Hosken, G.D., preceding paper in this Journal.

30
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- For similar transformations, reported after completion of the present work, see:
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32
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33
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- Protection of primary amines as N-substituted 2,5-dimethylpyrroles
- Protection as 2,5-dimethylpyrrole had been described previously by Meakins and co-workers. However, the deprotection conditions for this variant are somewhat vigorous. See:
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34
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- Künstliche molekulare Anion-Wirte. Die Synthese eines chiralen bicyclischen Guanidinium-Salzes als funktionalisierte Ankergruppe für Oxo-Anionen
- (1990) Chemische Berichte , vol.123 , pp. 907
- Gleich¹ Schmidtchen²

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