Cationic Zirconocene Olefin Polymerization Catalysts Based on the Organo-Lewis Acid Tris(pentafluorophenyl)borane. A Synthetic, Structural, Solution Dynamic, and Polymerization Catalytic Study

Journal of the American Chemical Society

Volumn 116, Issue 22, 1994, Pages 10015-10031

  Yang, Xinmin ^a   Stern, Charlotte L ^a   Marks, Tobin J ^a  

^a NORTHWESTERN UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

MOLECULAR STRUCTURE; OLEFINS; ORGANOMETALLICS; POLYMERIZATION; SYNTHESIS (CHEMICAL);

CATIONIC ZIRCONOCENE CATALYSTS; COMPLEXES; DIMERIZATION; LEWIS ACIDS;

CATALYSTS;

EID: 0028761731     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00101a022     Document Type: Article

References (45)

1. Boor, J. Ziegler-Natta Catalysts and Olefin Polymerization-, Academic Press: New York, 1979.
2. Erker, G.; Aulbach, M.; Kruger, C.; Werner, S. J. Organomet. Chem. 1993, 450, 1-7.
3. Farina, M.; Disilvestro, G. ; Sozzzni, P. Macromolecules 1993, 26, 946-950.
4. Girdello, M.A.; Eisen, M.S.; Stern, C.L.; Marks, T.J. J. Am. Chem. Soc. 1993, 115, 3326-3327.
5. Siedle, A.R.; Lamanna, W.M.; Olofson, J.M.; Nerad, B.A.; Newmark, R.A. ACS Symp. Ser. 1993, 517, 156-167.
6. Kaminsky, W.; Bark, A.; Steiger, R. J. Mol. Cat. 1992, 74, 109-119.
7. Okuda, J. Angew. Chem., Int. Ed. Engl. 1992, 31, 47-48.
8. Resconi, L.; Abis, L.; Franciscono, G. Macromolecules 1992, 25, 6814-6817.
9. Waymouth, R.; Pino, P. J. Am. Chem. Soc. 1990, 112, 4911-4914.
10. Ewen, J.A.; Jones, R.L.; Razavi, A.; Ferrara, J.D. J. Am. Chem. Soc. 1988, 110, 6255-6256.
11. Kaminsky, W. Kulper, K.; Brintzinger, H. Angew. Chem., Int. Ed. Engl. 1985, 24, 507-509.
12. Ginantti, E.; Nicoletti, G.M.; Mazzocchi, R. J. Poly. Sei: Poly Chem. Ed. 1985, 23, 2117-2133.
13. Ewen, J.A. J. Am. Chem. Soc. 1984, 106, 6355-6264.
14. Herwig, J.; Kaminsky, W. Polymer Bult. 1983, 9, 417.
15. Kaminsky, W.; Miri, M.; Sinn, H.; Woldt, R. Macromol. Chem. Rapid Commun. 1983, 4, 417-421.
16. Sinn, H.; Kaminsky, W. Adv. Organomet. Chem. 1980, 18, 99-149.
17. Long, W.P.; Breslow, D.S. J. Am. Chem. Soc. 1960, 82, 1953-1957.
18. Breslow, D.S.; Newburg, N.R. J. Am. Chem. Soc. 1957, 79, 5072.
19. Eisch, J.J.; Piotrowski, A.M.; Brownstein, S.K.; Gabe, E.J.; Lee, F.L. J. Am. Chem. Soc. 1985, 7, 7219-7200.
20. Gassman, P.G.; Callstrom, M.R. J. Am. Chem. Soc. 1987, 109, 7875-7876.
21. Tritto, I.; Li, S.; Sacchi, M.C.; Zannoni, G. Macromolecules 1993, 26, 7111-7115,
22. Eisch, J.J.; Caldwell, K.R.; Werner, S.; Kroger, K. Organometallics 1991, 10, 3417-3419.
23. Resconi, L.; Bossi, S.; Abis, L. Macromolecules 1990, 23, 4489-4491.
24. Sishta, C.; Hathorn, R.; Marks, T.J. J. Am. Chem. Soc. 1992, 114, 1112-1114.
25. Watson, P.L.; Parshall, W. Acc. Chem. Res. 1985, 8, 51-56,,
26. Fendrick, C.M.; Marks, T.J. J. Am. Chem. Soc. 1986, 108, 425-437.
27. Bunel, E.; Burger, B.J.; Bercaw, J.E. J. Am. Chem. Soc. 1988, 110, 976-978.
28. Burger, B.J.; Thompson, M.; Cotter, D.; Bercaw, J.E. J. Am. Chem. Soc. 1990, 122, 1566-1577.
29. Shapiro, P.J.; Cotter, W.D.; Schaefer, W.P.; Labinger, J.A.; Bercaw, J.E. J. Am. Chem. Soc. 1994, 116, 4623-4640.
30. Mason, M.R.; Smith, J.M.; Bott, S.G.; Barron, A.R. J. Am. Chem. Soc. 1993, 115, 4971-4984,,
31. Sugano, T.; Matsubara, K.; Fugita, T.; Takahashi, T.J. Mol. Catal. 1993, 82, 93-101.
32. Massey, A.G.; Park, A.J. J. Oranomet. Chem. 1964, 2, 245-250.
33. Massey, A.G.; Park, A.J. J. Organomet. Chem., 1966, 5, 218-225.
34. Yang, X.; Stern, C.L.; Marks, T.J. Angew. Chem., Int. Ed. Engl. 1992, 31, 1375-1377.
35. Yang, X.; Stern, C.L.; Marks, T. J. Angew. Chem., Int. Ed. Engl. 1992, 31, 1375-1377.
36. Yang, X.; Stern, C.L.; Marks, T.J. Organometallics 1991, 10, 840-842.
37. Cohen, S.E.; Massey, A.G. Adv. Fluorine Chem. 1970, 6, 149-162.
38. Treichel, P.M.; Stone, F.G.A. Adv. Organomet. Chem. 1964, 1, 143-216.
39. Jodan, R.F.; Bajyur, C.S.; Willett, R.; Scott, B. J. Am. Chem. Soc. 1986, 108, 7410-7411.
40. Ryan, M.F.; Siedle, A.R.; Burk, M.J.; Richardson, D.E. Organometallics 1992, 11, 4231-4237.
41. Richardson, D.E.; Ryan, M.F.; Khan, N.I.; Maxwell, K.A. J. Am. Chem. Soc. 1992, 114, 10482-10485.
42. Gassman, P.G.; Winter, C.H. Organometallics 1991, 10, 1592-1598.
43. Gassman, P.G.; Deck, P.A. Organometallics 1992, 11, 959-960.
44. Bush, M.A.; Sim, G.A. J. Chem. Soc. 1971, 2225-2229.
45. Tsutsui, T.; Mizuno, A.; Kashiwa, N. Polymer 1989, 30, 428-431.