Unified approach to living and non‐living cationic polymerization of alkenes

Polymer International

Volumn 35, Issue 1, 1994, Pages 1-26

  Matyjaszewski, Krzysztof ^a   Sigwalt, Pierre ^b  

^a CARNEGIE MELLON UNIVERSITY   (United States)

^b SORBONNE UNIVERSITÉ   (France)

Author keywords

carbocationic polymerization; carbocations; living polymerizations; termination reactions; transfer reactions

Indexed keywords

CHEMICAL REACTIONS; LOW TEMPERATURE EFFECTS; LOW TEMPERATURE OPERATIONS; MOLECULAR WEIGHT; OLEFINS;

CARBOCATIONS; LIVING CATIONIC POLYMERIZATION; NONLIVING CATIONIC POLYMERIZATION; TRANSFER REACTIONS;

CATIONIC POLYMERIZATION;

EID: 0028494535     PISSN: 09598103     EISSN: 10970126     Source Type: Journal    
DOI: 10.1002/pi.1994.210350101     Document Type: Article

References (132)

1. New processes and designed polymers by cationic techniques
2. Recent Results in Proton-Initiated and Non Proton-Initiated Cationic Polymerizations
3. Identification of some carbocationic active species: Structure and stability relationship
4. 895. Cationic and pseudocationic polymerisation of aromatic olefins. Part I. Kinetics and mechanism of the pseudocationic polymerisation of styrene by perchloric acid
5. Activated esters in the cationic polymerization of styrenes
6. Free-Cationic Polymerization of Styrere by Radiation
7. Pseudo-cationic polymerisation after 24 years
8. Comments on “pseudocationic polymerization after 24 years” by P. H. Plesch
9. A novel high-vacuum and variable-temperature stopped-flow device for high-purity polymerization kinetics
10. Carbenium ions, onium ions, and covalent species in the cationic polymerization of alkenes
11. Cationic polymerization of alkenes and heterocyclics. More similarities than differences
12. Kinetic Study of the Polymerization of Alkyl Vinyl Ethers by HI/12Catalyst
13. Living cationic polymerization of vinyl ethers
14. Cationoid living polymerisations
15. Living cationic polymerization of vinyl ethers and styrene derivatives: Design of initiating systems based on added salts with halogen anions
16. Fundamental studies on cationic polymerizations: Molecular weights and molecular weight distributions of polyisobutylenes produced by γ-irradiation (free ions) and chemical catalysis (ion pairs)
17. 42. The low-temperature polymerisation of isobutene. Part VI. Polymerisation by titanium tetrachloride and water in methylene dichloride
18. 1041. The polymerisation of styrene by titanium tetrachloride. Part IV. Kinetics of polymerisation in methylene dichloride
19. Electron-Pair Donors in Carbocationic Polymerization. III. Carbocation Stabilization by External Electron-Pair Donors in Isobutylene Polymerization
20. Cationic polymerization of isobutyl vinyl ether initiated with the system aluminium trichloride/ethyl acetate, in toluene solution
21. Polyisobutylene-containing block polymers by sequential monomer addition. I. The living carbocationic polymerization of styrene
22. New initiators for living cationic polymerization of vinyl compounds
23. The Polymerization of Styrene by Sulphuric Acid. I. Theory of Fast-Initiated Non-Stationary Polymerization
24. Carbon-13 N.M.R. studies of carbocations. II. An investigation of the correlation between carbon chemical shifts and σ+constants for 1-phenylethyl cations
25. The racemisation of (?)-1-phenylethyl chloride by stannic chloride in carbon tetrachloride and its bearing on the cationic polymerisation of styrene
26. Acceptor properties of metal halides. Part V. Stannic chloride as a catalyst for the racemisation of ?-methylbenzyl chloride in benzene solution, and the effect of hydrogen chloride on the catalysed reaction
27. Relative Reaktivität konjugierter Alkene gegenüber Diarylcarbenium-Ionen
28. Direct observation and stability of active species in cationic polymerization: A reexamination of the polymerization of styrene initiated by triflic acid
29. The role of association/complexation equilibria in the anionic polymerization of (meth)acrylates
30. Quantitative aspects of the Lewis acidity of covalent metal halides and their organo derivatives