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Volumn 116, Issue 16, 1994, Pages 7369-7377

IR Flash Kinetic Spectroscopy of C-H Bond Activation of Cyclohexane-do and -d12 by Cp∗Rh(CO)2 in Liquid Rare Gases: Kinetics, Thermodynamics, and an Unusual Isotope Effect

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL ACTIVATION; INERT GASES; INFRARED SPECTROSCOPY; ORGANOMETALLICS; REACTION KINETICS; RHODIUM COMPOUNDS; THERMODYNAMICS;

EID: 0028493481     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00095a047     Document Type: Article
Times cited : (153)

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    • Note added in proof: Two recent studies report hydrocarbon-metal binding and /or activation isotope effects that are relevant to our observations: (a) the measurement of intra- vs intermolecular isotope effects on methane activation in early transition metal systems by
    • Note added in proof: Two recent studies report hydrocarbon-metal binding and /or activation isotope effects that are relevant to our observations: (a) the measurement of intra- vs intermolecular isotope effects on methane activation in early transition metal systems by Schaller, C. P.; Bonanno, J. B.; Wolczanski, P. T. J. Am. Chem. Soc. 1994, 116, 4133;
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