Kinetics and mechanism of the oxidation of sulfur (IV) by peroxomonosulfuric acid anion

Atmospheric Environment

Volumn 28, Issue 3, 1994, Pages 439-448

  Elias, Horst ^a   Götz, Uwe ^a   Wannowius, Klaus J ^a  

^a DARMSTADT UNIVERSITY OF TECHNOLOGY   (Germany)

Author keywords

general acid catalysis; kinetics and mechanism; Oxidation of S(IV); peroxomonosulfuric acid

Indexed keywords

CATALYSIS; KINETICS; PEROXOMONOSULPHURIC ACID; SULPHUR IV OXIDATION;

ABSORPTION SPECTROSCOPY; CATALYSIS; IONS; OXIDATION; PH EFFECTS; REACTION KINETICS; SPECTROPHOTOMETRY; SULFURIC ACID; ULTRAVIOLET SPECTROSCOPY;

PEROXOMONOSULFURIC ACID ANION; RATE LAW EQUATION; STOPPED FLOW SPECTROPHOTOMETRY;

SULFUR;

ANION; BUFFER; SODIUM SULFATE; SULFUR; SULFUR DIOXIDE; SULFURIC ACID;

AQUEOUS SOLUTION; ARTICLE; CATALYSIS; CHEMICAL REACTION KINETICS; DISSOCIATION CONSTANT; EQUILIBRIUM CONSTANT; OXIDATION; PH; PRIORITY JOURNAL; PROTON TRANSPORT; SPECTROPHOTOMETER;

EID: 0028372601     PISSN: 13522310     EISSN: None     Source Type: Journal    
DOI: 10.1016/1352-2310(94)90122-8     Document Type: Article

References (25)

1. The kinetics and mechanism of the decomposition of Caro's acid (Part I)
2. 2 by peroxomonosulfate
3. Photolysis of nitric acid in solid argon: the infrared absorption of peroxynitrous acid (HOONO)
4. −
5. 2
6. Kinetic investigation of sulfur(IV) oxidation by peroxo compounds R-OOH in aqueous solution
7. Kinetics and mechanism of sulfur(IV) oxidation by hydrogen peroxide in aqueous phase the non-linear parts of the pH-profile
8. Decomposition of inorganic peroxyacids in aqueous alkali
9. Atmospheric oxidation of hydrocarbons: formation of hydroperoxides and peroxyacids
10. Kinetics of the oxidation of sulfite by hydrogen peroxide in acidic solution
11. Chemistry of OH in remote clouds and its role in the production of formic acid and peroxymonosulfate
12. Decomposition of pernitric acid in aqueous solution
13. Aqueous phase oxidation of sulfur(IV) by hydrogen peroxide methylhydroperoxide and peroxoacetic acid
14. Kinetics and mechanism of the oxidation of aquated sulfur dioxide by hydrogen peroxide at low pH
15. Kinetics of the hydrogen peroxide-sulfite reaction in alkaline solution
16. The free-radical decomposition of peroxymonosulfate
17. Aqueous oxidation of sulfur dioxide by hydrogen peroxide at low pH
18. Nucleophilic substitution on nitrogen. Kinetics of reactions of hydroxylamine-O-sulfonic acid in dimethyl sulfoxide-water solvents
19. Peroxidisulphate oxidations 2. Kinetics and mechanism of the peroxodisulphate-sulphur(IV) reaction
20. Chemical reactions in clouds