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Volumn 35, Issue 17, 1994, Pages 2663-2666

Acid catalyzed intramolecular Diels-Alder reactions in lithium perchlorate-diethyl ether: Enhanced reaction rates and diastereoselectivity

Author keywords

[No Author keywords available]

Indexed keywords

NAPHTHALENE DERIVATIVE; POLYCYCLIC HYDROCARBON;

EID: 0028271324     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(00)77000-6     Document Type: Article
Times cited : (44)

References (15)
  • 5
    • 0027380321 scopus 로고
    • Diels-alder reactions enhanced diastereofacial selectivity in 5.0 M LiClO4-Et2O approach to the construction of the isoindolone nucleus of cytochalasans
    • (1993) Tetrahedron Letters , vol.34 , pp. 7367
    • Grieco1    Beck2
  • 6
    • 84912906808 scopus 로고
    • For recent reviews on the intramolecular Diels-Alder reaction see
    • (1984) Org. Reactions , vol.32 , pp. 1
    • Ciganek1
  • 8
    • 0013176884 scopus 로고
    • Stereoselectivities of thermal and Lewis acid catalyzed intramolecular Diels-Alder reactions of internally activated dienophiles to form 5–11 membered rings
    • (1986) Tetrahedron Letters , vol.27 , pp. 4877
    • Smith1    Sakan2    Houk3
  • 10
    • 84912902811 scopus 로고    scopus 로고
    • 6 by treatment with 2-propenyl magnesium bromide in tetrahydrofuran followed by PCC oxidation.
  • 12
    • 0027192255 scopus 로고
    • Catalysis by lithium perchlorate in dichloromethane: Diels-Alder reactions and 1,3-Claisen rearrangements
    • (1993) Tetrahedron , vol.49 , pp. 6025
    • Reetz1    Gansäuer2
  • 13
    • 84912925898 scopus 로고    scopus 로고
    • We have examined a number of intramolecular Diels-Alder reactions in methylene chloride containing 1–30 mol% of lithium perchlorate and found that in the majority of cases studied reactions do not proceed to any appreciable extent (<10%) after 24 h at ambient temperature. (Unpublished work of S.T. Handy, Indiana University).
  • 14
    • 84912911708 scopus 로고    scopus 로고
    • 10


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.