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Tetrahedron
Volumn 50, Issue 10, 1994, Pages 3195-3212
Rhodium-carbenoid mediated O-H insertion reactions. O-H insertion vs. H-abstraction and effect of catalyst
Author keywords

[No Author keywords available]
Indexed keywords

ETHER DERIVATIVE; PHOSPHONIC ACID DERIVATIVE;
EID: 0028220862     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(01)81117-0     Document Type: Article
Times cited : (71)
References (59)
  • 2
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    • (1987) Top. Curr. Chem. , vol.137 , pp. 75-253
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  • 14
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    • Rhodium(II) Trifluoroacetamide; an Excellent Catalyst for Carbenoid O-H Insertion Reactions
    • (1992) Synlett , vol.12 , pp. 975-976
    • Cox1    Kulagowski2    Moody3    Sie4
  • 35
    • 85065202701 scopus 로고
    • Recent Synthetic Methods in Diazo Chemistry
    • (1972) Synthesis , pp. 351-373
    • Regitz1
  • 37
    • 84981750529 scopus 로고
    • C-Alkylierung von Silber-diazoessigsäure-äthylester und Silberdiazoketonen mit SN1-aktiven Halogeniden
    • (1969) Chemische Berichte , vol.102 , pp. 488-493
    • Schöllkopf1    Rieber2
  • 38
    • 84956094298 scopus 로고
    • Einwirkung von Säurechloriden auf Diazoessigester
    • We thank Mr M. C. Elliott, Loughborough University of Technology, who prepared the diazo amide (for details of this preparation see the Experimental section). For relevant literature see, We thank Professor A. Padwa (Emory University, Atlanta, USA) for an improved method for the preparation of ethyl diazomalonyl chloride
    • (1916) Berichte der deutschen chemischen Gesellschaft , vol.49 , pp. 1978
    • Staudinger1    Becher2    Hirzel3
  • 39
    • 84914010194 scopus 로고    scopus 로고
    • This compound was prepared by a method devised by Mr K.J. Doyle, Loughborough University of Technology, according to which the diazo precursor was synthesised by heating the sodium salt of benzenesulfinic acid with ethyl bromoacetate which was followed by diazo transfer using 4-acetamidobenzenesulfonyl azide or 1-ethyl-2-chloropyridinium tetrafluoroborate (15) and sodium azide.
  • 42
    • 85023146176 scopus 로고
    • Horner-Wittig Synthesis of α, β-Unsaturated Sulfides and Sulfones. Part II
    • (1970) Synthesis , pp. 145-149
    • Shahak1    Almog2
  • 46
    • 0001273370 scopus 로고
    • Untersuchungen an Diazoverbindungen, VII. Vergleichende kinetische Untersuchungen zur thermischen Stabilität aliphatischer Diazoverbindungen
    • (1970) Chemische Berichte , vol.103 , pp. 1477-1485
    • Regitz1    Bartz2
  • 48
    • 84914010193 scopus 로고    scopus 로고
    • During the period of time in which this work was carried out we became aware of similar studies being undertaken by workers at SmithKline Beecham, see preceding paper.
  • 54
    • 84914010192 scopus 로고    scopus 로고
    • We thank Professor M. A. McKervey, Queens University of Belfast, for the donation of samples of these chiral rhodium catalysts.
  • 56
    • 84989540658 scopus 로고
    • Rhodium(II) Carboxylates: Novel Highly Efficient Catalysts for the Cyclopropanation of Alkenes with Alkyl Diazoacetates
    • (1976) Synthesis , pp. 600-602
    • Hubert1    Noels2    Anciaux3    Teyssié4
  • 58
    • 84914010191 scopus 로고    scopus 로고
    • The isopropyloxy malonate has been prepared from the corresponding diazo compound by a method analogous to that of the diethyl analogue 23. The details of this compound are described in the experimental section of this paper.
  • 59
    • 84914010190 scopus 로고    scopus 로고
    • We are grateful to Professor R. Grigg, University of Leeds, for drawing our attention to this possibility.

* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.