Elaboration of zirconacyclopentanes by sequential insertion of lithium chloroallylide and ketones or aldehydes

Tetrahedron Letters

Volumn 35, Issue 5, 1994, Pages 785-788

  Luker, Tim ^a   Whitby, Richard J ^a  

^a UNIVERSITY OF SOUTHAMPTON   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

CYCLOPENTANE DERIVATIVE;

ARTICLE; DRUG SYNTHESIS; NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 0028118774     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(00)75817-5     Document Type: Article

References (25)

1. Zirconocene-promoted stereoselective bicyclization of 1,6- and 1,7-dienes to produce trans-zirconabicyclo[3.3.0]octanes and cis-zirconabicyclo[4.3.0]nonanes
2. Remarkably pair- and regioselective carbon-carbon bond-forming reaction of zirconacyclopentane derivatives with Grignard reagents
3. Zirconium-mediated ring construction from dienes: remarkable effect of ligands on stereochemistry
4. On the reversibility of alkene cyclozirconation
5. Novel synthesis of nitrogen heterocycles using zirconium-promoted reductive coupling. Formal total synthesis of dendrobine
6. Template synthesis of substituted cyclopentanones by zirconocene/olefin/CO systems
7. Zirconium-catalyzed diene and alkyl-alkene coupling reactions with magnesium reagents
8. Formation of zirconocene η2-imine complexes by rearrangement of cyclic iminoacyl complexes.
9. Migratory insertion reactions of organometallics. 3. Carbon-carbon bond forming reactions of organotransition metals with .alpha.- or .gamma.-haloorganolithium reagents
10. The reaction of thermally generated (ethylene)hafnocene with methylenetriphenylphosphorane: competing reaction paths leading to Cp2HfC2H5(CH:PPh3) and a hafnacyclobutane
11. Synthesis of homopropargylic and .alpha.-allenic alcohols from lithium chloropropargylide, trialkylboranes, and aldehydes
12. Synthetic applications of metallate rearrangements
13. .eta.3-Bonding of phenylallenyl in a zirconocene complex
14. Organoboranes. 54. Exploration of the reactions of (.alpha.-haloallyl)lithium with organoborane derivatives. Simple and convenient procedure for the synthesis of three-carbon homologated boronate esters and terminal alkenes
15. Three-carbon ring expansion of boracyclanes
16. Die Reaktion von (Butadien)zirconocen und -hafnocen mit Ethylen
17. Regio- and stereochemistry in the sequential insertion of carbonyl compounds into zirconium-diene complexes
18. Grignard-type addition of alkenyl- and alkylzirconocene chloride to aldehyde: Remarkable catalytic acceleration effect of AgClO4
19. Preparation and regio- and diastereoselective reactions of allylic zirconium reagents from allylic ether derivatives
20. The Use of Diethyl Azodicarboxylate and Triphenylphosphine in Synthesis and Transformation of Natural Products
21. Stereoselective .alpha.-alkylation of metallacyclic zirconoxycarbene complexes - a case of asymmetric 1,5-induction