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Volumn 24, Issue 22, 1994, Pages 3277-3287

Double asymmetric induction in intramolecular c-h insertion reactions of α-diazo ß-keto esters

Author keywords

[No Author keywords available]

Indexed keywords

CYCLOPENTANONE DERIVATIVE;

EID: 0028116991     PISSN: 00397911     EISSN: 15322432     Source Type: Journal    
DOI: 10.1080/00397919408010251     Document Type: Article
Times cited : (26)

References (27)
  • 1
    • 18444417883 scopus 로고
    • For reviews, see: (a)
    • For reviews, see: (a) Doyle, M. P. Chem. Rev. 1986, 86, 919;
    • (1986) Chem. Rev , vol.86 , pp. 919
    • Doyle, M.P.1
  • 2
    • 0012887591 scopus 로고
    • Acc. Chem. Res. 1986, 19, 348.
    • (1986) Acc. Chem. Res , vol.19 , pp. 348
  • 13
    • 0000719854 scopus 로고
    • For a diastereoselective intramolecular C-H insertion of chiral a-diazo ß-keto esters, see: (a)
    • For a diastereoselective intramolecular C-H insertion of chiral a-diazo ß-keto esters, see: (a) Taber, D. F., Raman, K. J. Am. Chem. Soc. 1983, 105, 5935.
    • (1983) J. Am. Chem. Soc , vol.105 , pp. 5935
    • Taber, D.F.1    Raman, K.2
  • 15
    • 84963385146 scopus 로고
    • There have been recorded many examples of chiral Cu(D-and Rh(II)-catalyzed cyclopropanation of olefins with chiral diazoacetates in which the chirality of the catalyst is the dominating factor for the stereochemical course of this process. Compared to the use of the chiral Cu(I) catalysts, the catalyses with chiral Rh(II) complexes frequently exhibit significant levels of double stereodifferentiation. (a) For double asymmetric cyclopropanation with chiral Cu(I) catalysts, see: (i)
    • There have been recorded many examples of chiral Cu(D-and Rh(II)-catalyzed cyclopropanation of olefins with chiral diazoacetates in which the chirality of the catalyst is the dominating factor for the stereochemical course of this process. Compared to the use of the chiral Cu(I) catalysts, the catalyses with chiral Rh(II) complexes frequently exhibit significant levels of double stereodifferentiation. (a) For double asymmetric cyclopropanation with chiral Cu(I) catalysts, see: (i) Aratani, T. Pure Appl. Chem. 1985, 57, 57.
    • (1985) Pure Appl. Chem , vol.57 , pp. 57
    • Aratani, T.1
  • 23
    • 84963295373 scopus 로고
    • For the substituent effects at the insertion site on enantioselectivities in intramolecular C-H insertion reactions, see: in press.
    • For the substituent effects at the insertion site on enantioselectivities in intramolecular C-H insertion reactions, see: Hashimoto, S., Watanabe, N., Ikegami, S. Synlett 1994, in press.
    • (1994) Synlett
    • Hashimoto, S.1    Watanabe, N.2    Ikegami, S.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.