SCOPUS 정보 검색 플랫폼

Volumn 5, Issue 8, 1994, Pages 1513-1518

Asymmetric methylene transfer reactions I: Asymmetric synthesis of oxiranes from carbonyl compounds by methylene transfer reaction using chiral S-methyl-S-neomenthyl-N-tosyl sulfoximines

(2) Taj, Shabbirali S a Soman, Raghavan a

a Malti Chem Research Centre (India)

Author keywords

[No Author keywords available]

Indexed keywords

ETHYLENE OXIDE DERIVATIVE;

ARTICLE; DRUG SYNTHESIS; ENANTIOMER; PRIORITY JOURNAL; REACTION ANALYSIS;

EID: 0028040777 PISSN: 09574166 EISSN: 1362511X Source Type: Journal
DOI: 10.1016/0957-4166(94)80120-7 Document Type: Article

Times cited : (14)

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- The Absolute configuration at sulfur is not determined. Hence diastereomers are referred to as 9a and 9b with specific rotation characterising them. Determination of absolute configuration at sulfur of the sulfoxides 9a and 9b, and of the sulfoximines 10a and 10b and relating this with the configuration of the oxiranes will form the subject matter of a subsequent paper in this series.

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- 1H NMR spectra of these diastereomeric sulfoxides is that the C-3 proton of the crystalline isomer 9a, appears at δ 2.80 whereas in the liquid isomer, 9b, it appears at δ 3.28.

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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.