Selective deprotective method using palladium-water soluble catalysts

Tetrahedron Letters

Volumn 35, Issue 47, 1994, Pages 8783-8786

  Lemaire Audoire, Sandrine ^a   Savignac, Monique ^a   Blart, Errol ^a   Pourcelot, Guy ^a   Genêt, Jean Pierre ^a   Bernard, Jean Marie ^b  

^a Ecole Nationale Superieure de Chimie de Lille   (France)

^b SANOFI   (France)

Author keywords

Allyloxycarbonyl and Allylcarboxy groups; Deprotection; Palladium aqueous catalyst

Indexed keywords

AMINE; CARBOXYLIC ACID DERIVATIVE; PIPERIDINE DERIVATIVE; PYRROLIDINE DERIVATIVE;

ARTICLE; DRUG SYNTHESIS; METHODOLOGY; REACTION ANALYSIS;

EID: 0028020528     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(00)78497-8     Document Type: Article

References (16)

1. Palladium-Catalyzed Cross-Coupling Reactions in a Homogeneous Aqueous Medium
2. Palladium-catalyzed reactions in aqueous media. An efficient removal of allyloxycarbonyl protecting group from oxygen and nitrogen
3. Practical palladium-mediated deprotective method of Allyloxycarbonyl in aqueous media
4. The allylic protection method in solid-phase oligonucleotide synthesis. An efficient preparation of solid-anchored DNA oligomers
5. Homogeneous, palladium(0)-catalyzed exchange deprotection of allylic esters, carbonates and carbamates
6. The Allyl Ester as Carboxy-Protecting Group in the Stereoselective Construction of Neuraminic-Acid Glycosides
7. The allyloxycarbonyl group for alcohol protection: quantitative removal or transformation into allyl protecting group via π-allyl complexes of palladium
8. On the use of silylated nucleophiles in the palladium catalysed deprotection of allylic carboxylates and carbamates.
9. Mild and selective palladium(0)-catalyzed deallylation of allylic amines. Allylamine and diallylamine as very convenient ammonia equivalents for the synthesis of primary amines
10. Palladium-catalyzed alkylations in aqueous media
11. Palladium(0)-Catalyzed Substitution of Allylic Substrates in a Two-Phase Aqueous-Organic Medium
12. Synthesis of substituted cinnamic acids and cinnamonitriles via palladium catalyzed coupling reactions of aryl halides with acrylic acid and acrylonitrile in aqueous media