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Tetrahedron Letters

Volumn 35, Issue 51, 1994, Pages 9549-9552

Rhodium(II)-vinylcarbenoid insertion into the SiH bond. A new stereospecific synthesis of allylsilanes

(3) Landais, Yannick a Planchenault, Denis a Weber, Valéry a

a UNIVERSITY OF LAUSANNE (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

SILANE DERIVATIVE;

ARTICLE; CATALYSIS; DRUG SYNTHESIS; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 0027939290 PISSN: 00404039 EISSN: None Source Type: Journal
DOI: 10.1016/0040-4039(94)88508-7 Document Type: Article

Times cited : (54)

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- 2). Similarly, diazoester 3f was prepared from the corresponding ester, obtained by the following sequence :

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20
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21
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22
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- Diastereoselectivity in the OH insertion reactions of rhodium carbenoids derived from phenyldiazoacetates of homochiral alcohols
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25
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- 2] to give the corresponding methyl-2-hydroxy-4-phenylbutanoate, Both sequences gave some epimerization (20–30%), but allowed us to assign unambiguously the (S) configuration for 5a–c and 5e.
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