Sorption of Organics from Aqueous Solution onto Polymeric Resins

Industrial and Engineering Chemistry Research

Volumn 32, Issue 11, 1993, Pages 2727-2735

  Gusler, Gloria M ^a   Browne, Thomas E ^a   Cohen, Yoram ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATED CARBON; AROMATIC COMPOUNDS; PHENOLS; POLYMERS; POROSITY; SOLUTIONS; SORPTION; SWELLING; TOLUENE;

BENZOIC ACID; CHLOROBENZENE; SOLUTE UPTAKE;

WATER TREATMENT;

ADSORPTION; RESINS; SEPARATION;

EID: 0027693107     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie00023a040     Document Type: Article

References (68)

1. Allen, D. T. (Department of Chemical Engineering, University of California, Los Angeles, Los Angeles CA, 90024). Personal communication, April 23, 1992.
2. Barton, A. F., Ed. Handbook of Solubility Parameters and Other Cohesion Parameters; Chemical Rubber Co. Press: Boca Raton, FL, 1983.
3. Belfort, G.; Altshuler, G. L.; Thallam, K. K.; Feerick, C. P.; Woodfield, K. L. Selective Adsorption of Organic Homologues onto Activated Carbon from Dilute Aqueous Solutions. Solvophobic Interaction Approach — V The Effect of Simple Structural Modifications with Aromatics. In Fundamentals of Adsorption; Myers, A. L., Belfort, G., Eds.; Engineering Floundation: 345 E. 47th St, New York, NY, 1984; pp 77–94.
4. Browne, T. E.; Cohen, Y. Aqueous-Phase Adsorption of Trichloroethene and Chloroform onto Polymeric Resins and Activated Carbon. Ind. Eng. Chem. Res. 1990, 29, 1338–1345.
5. Brunauer, S.; Emmett, P. H.; Teller, E. Adsorption of Gases in Multicomponent Layers. J. Am. Chem. Soc. 1938, 60, 309–319.
6. Cairo, P. R.; Coyle, J. T.; Davis, J. T.; Neukrug, H. M.; Suffet, I. H.; Wickland, A. Evaluating Regenerated Activated Carbon Through Laboratory and Pilot-Column Studies. J. Am. Water Works Assoc. 1982, 74 (2), 94–102.
7. Chanda, M.; O'Driscoll, K. F.; Rempel, G. L. Sorption of Phenolics onto Cross-Linked Poly(4-vinylpyridine). React. Polym. 1983, 1, 39–48.
8. Chanda, M.; O'Driscoll, K. F.; Rempel, G. L. Sorption of Phenolics and Carboxylic Acids on Polybenzimidazole. React. Polym. 1985, 4, 39–48.
9. Coasta, E.; Calleja, G.; Marijuan, L. Comparative Adsorption of Phenol, P-Nitrophenol and P-Hydroxybenzoic Acid on Activated Carbon. Adsorp. Sci. and Technol. 1988, 5 (3), 213–228.
10. Cornel, P.; Sontheimer, H. Sorption of Dissolved Organics from Aqueous Solution by Polystyrene Resins-I. Resin Characterization and Sorption Equilibrium. Chem. Eng. Sci., 1986, 41 (7), 1791–1800.
11. Dinopoulou, G. Sorptive Behavior of a Multicomponent Solution of Phenolics with Synthetic Resin. M.S. Thesis, Illinois Institute of Technology, 1985.
12. Dobbs, R. A.; Cohen, J. M. Carbon Adsorption Isotherms for Toxic Organics; EPA-600/8-80-023; Municipal Environmental Research Laboratory, Office of Research and Development, Environmental Protection Agency, U.S. Government Printing Office: Washington, DC, April 1980.
13. Dubinin, M. M. Adsorption in Micropores. J. Colloid Interface Sci. 1967, 23, 487–499.
14. Flory, P. J. Principles of Polymer Chemistry; Cornell University Press: Ithaca, NY, 1953.
15. Garcia, A. A.; King, C. J. The Use of Basic Polymer Sorbents for the Recovery of Acetic Acid from Dilute Aqueous Solution. Ind. Eng. Chem. Res. 1989, 28, 204–212.
16. Grant, T. M. Irreversible Adsorption of Phenolic Compounds by Activated Carbons. Ph.D. Thesis, Department of Chemical Engineering, University of California, Berkeley, 1988.
17. Grant, T. M.; King, C. J. Mechanism of Irreversible Adsorption of Phenolic Compounds by Activated Carbons. Ind. Eng. Chem. Res. 1990, 29, 264–271.
18. nd ed; Academic Press: London, 1982.
19. Grulke, E. A. Solubility Parameter Values. In Polymer Handbook, 3rd ed.; Brandup, J., Immergut, E. H., Eds.; John Wiley & Sons: New York, 1989; p 519.
20. Gusler, G. M. Removal of Organics from Aqueous Solutions using Polymeric Resins. Ph. D. Thesis, University of California, Los Angeles, in preparation.
21. Gustafson, R. L.; Albright, R. L.; Heisler, J.; Lirio, J. A.; Reid, O. T., Jr. Adsorption of Organic Species by High Surface Area Styrene-Divinylbenzene Copolymers. Ind. Eng. Chem. Process Des. and Dev. 1968, 7 (2), 107–115.
22. Hacskaylo, J. J.; LeVan, M. D. Correlation of Adsorption Equilibrium Data Using a Modified Antoine Equation: A New Approach for Pore-Filling Models. Langmuir. 1985, 1, 97–100.
23. Hasanain, M. A.; Hines, A. L. Application of the Adsorption Potential Theory to Adsorption of Carboxylic Acids from Aqueous Solutions onto a Macroreticular Resin. Ind. Eng. Chem. Process Des. Dev. 1981, 20 (4), 621–25.
24. 7; Kertes, A. S., Ed.; IUPAC Solubility Data Series; Pergamon Press: Oxford, New York, 1989; Vol 37, pp 369-341.
25. nd ed.; Marcel Dekker, Inc.: New York, 1986.
26. Hofer, L. J. E.; Manes, M. Adsorption on Activated Carbon from Solvents of Different Refractive Index. Chem. Eng. Prog. Symp. Ser. 1969, 65 (96), 84–88.
27. Honrath, A. L. Chlorobenzene. In Halogenated Benzenes, Toluenes, and Phenols with Water; Kertes, A. S., Ed.; IUPAC Solubility Data Series; Pergamon Press: Oxford, New York, 1985; Vol. 20, pp 153–182.
28. Howard, P. H. Handbook on Environmental Fate and Exposure Data for Organic Chemicals; Lewis Publishers, Inc.: Chelsea, MI, 1989.
29. Itaya, A.; Kato, N.; Yamamoto, J.; Okamoto, K. Liquid Phase Adsorption Equilibrium of Phenol and its Derivatives on Macroreticular Adsorbents. J. Chem. Eng. Jpn. 1984, 17 (4), 389–395.
30. Jaroniec, M.; Patrykiejev, A.; Borowko, M. Statistical Thermodynamics of Monolayer Adsorption from Gas and Liquid Mixtures on Homogeneous and Heterogeneous Solid Surfaces. Prog. Surf. Membr. Sci. 1981, 14, 1–68.
31. Jossens, L.; Prausnitz, J. M.; Fritz, W.; Schlünder, E. U.; Myers, A. L. Thermodynamics of Multi-solute Adsorption form Dilute Aqueous Solutions. Chem. Eng. Sci. 1978, 33, 1097–1106.
32. Kawabata, N.; Ohira, K. Removal and Recovery of Organic Pollutants from Aquatic Environment. 1. Vinylpyridine — Divinylbenzene Copolymer as a Polymeric Adsorbent for Removal and Recovery of Phenol from Aqueous Solution. Environ. Sci. Tech. 1979, 13 (1), 1396–1402.
33. Kunin, R. Polymeric Adsorbents for Treatment of Waste Effluents. Polym. Eng. Sci. 1977, 17 (1), 58–62.
34. Langmuir, I. The Adsorption of Gases on Plane Surfaces of Glass, Silica, and Mica. J. Am. Chem. Soc. 1918, 40, 1361–1403.
35. Lowell, S.; Shields, J. E. Powder Surface Area and Porosity, 2nd ed.; Chapman and Hall: New York, 1984.
36. Maity, N.; Payne, G. F.; Chipchosky, J. L. Adsorptive Separations Based on the Differences in Solute-Sorbent Hydrogen Bonding Strengths. Ind. Eng. Chem. Res. 1991, 30, 2456–2463.
37. Manes, M. The Polanyi Adsorption Potential Theory and its Applications to Adsorption from Water Solution onto Activated Carbon. In Activated Carbon Adsorption of Organics from the Aqueous Phase; Suffet, I. H., McGuire, M. J., Eds.; Ann Arbor Science Publishers: Ann Arbor, MI, 1980; Vol. 1, Chapter 2, pp 43–63.
38. Manes, M.; Hofer, L. J. E. Application of the Polanyi Adsorption Potential Theory to Adsorption from Solution on Activated Carbon. J. Phys. Chem. 1969, 73 (3), 584–590.
39. McClellan, A. L.; Harnsberger, H. F. Cross-Sectional Areas of Molecules Adsorbed on Solid Surfaces. J. Colloid Interface Sci. 1967, 23, 577–599.
40. McGuire, M. I.; Suffet, I. H. Adsorption of Organics from Domestic Water Supplies. J. Am. Water Works Assoc. 1978, 70, 621.
41. McGuire, M. J.; Suffet, I. H. The Calculated Net Adsorption Energy Concept. In Activated Carbon Adsorption of Organics from the Aqueous Phase; Suffet, I. H., McGuire, M. J. Eds.; Ann Arbor Science Publishers: Ann Arbor, MI, 1980; Vol. 1.
42. McGuire, M. J.; Suffet, I. H.; Radziul, J. V. Assessment of Unit Processes for the Removal of Trace Organic Compounds from Drinking Water. J. Am. Water Works Assoc. 1978, 70 (10), 565–572.
43. Neely, J. W. A Model for the Removal of Trihalomethanes from Water by Ambersorb XE-340. In Activated Carbon Adsorption of Organics from the Aqueous Phase; Ann Arbor Science Publishers: Ann Arbor, MI, 1980; Vol. 2, Chapter 17, pp 417–424.
44. Nirmalakhandan, N.; Speece, R. E. Prediction of Aqueous Solubility of Organic Chemicals Based on Molecular Structure — II. Applications to PNAs, PCBs, PCDDs, etc. Environ. Sci. Technol. 1989, 23 (6), 708–713.
45. Paleos, J. Adsorption from Aqueous and Nonaqueous Solutions on Hydrophobic and Hydrophilic High Surface — Area Copolymers. J. Colloid and Interface Sci. 1969, 31 (1), 7–18.
46. Payne, G. F.; Ninomiya, Y. Selective Adsorption of Solutes Based on Hydrogen Bonding. Sep. Sci. Technol. 1990, 26, (11, 12), 1117–1129.
47. Polanyi, M. Section III — Theories of the Adsorption of Gases. A General Survey and Some Additional Remarks. Trans. Faraday Soc. 1932, 28, 316–333.
48. Ram, N. M.; Morris, J. C. Selective Passage of Hydrophilic Nitrogenous Organic Materials through Macroreticular Resins. Environ. Sci. Techn. 1982, 16, 170–174.
49. Rixey, W. G. Non-Wet Adsorbents for the Selective Recovery of Polar Organic Solutes from Dilute Aqueous Solution. Ph.D. Thesis, Department of Chemical Engineering, University of California, Berkeley, 1987.
50. Rixey, W. G.; King, C. J. Non-Wetting Adsorbents for the Recovery of Solutes from Dilute Aqueous Solutions. In Fundamentals of Adsorption, Liapis, A. I., Ed.; Engineering Foundation: New York, 1987.
51. Sips, R. On the Structure of a Catalyst Surface. J. Chem. Phys. 1948, 16 (5), 490–495.
52. Speth, T. F. Predicting Equilibria for Single Solute and Multicomponent Aqueous-Phase Adsorption onto Activated Carbon. M.S. Thesis, Michigan Technological University, 1986.
53. Speth, T. F.; Miltner, R. J. Technical Note: Adsorption Capacity of GAC for Synthetic Organics. J. Am. Water Works Assoc. 1990, February, 72–75.
54. Suffet, I. H. An Evaluation of Activated Carbon for Drinking Water Treatment: A National Academy of Science Report. J. Am. Water Works Assoc. 1980, 72 (1), 41–50.
55. Suffet, I. H.; Brenner, L.; Coyle, J. T.; Cairo, P. R. Evaluation of the Capability of Granular Activated Carbon and XAD-2 Resin to Remove Trace Organics from Treated Drinking Water. Environ. Sci. Technol. 1978, 12 (12), 1315–1322.
56. Suffet, I. H.; Baker, R. J.; Yohe, T. L. Pretreatment of Drinking Water to Control Organic Contaminants and Taste and Odor. In Pretreatment in Chemical Water and Wastewater Treatment; Hahn, H. H., Klute, R., Eds.; Springer-Verlag: Berlin, Heidelberg, 1988.
57. Suwanayuen, S.; Danner, R. P. A Gas Adsorption Isotherm Equation Based on Vacancy Solution Theory. Am. Inst. Chem. Eng. J. 1980, 26 (1), 69–74.
58. Tedaldi, D. J.; Rogers, J. Polanyi Theory: Application to Sorption of Volatile Organic Compounds onto Soil under Varying Humidity Conditions. ASCE 1991 National Conference on Environmental Engineering.
59. Thurman, C. Phenol. In Kirk-Othmer Encyclopedia of Chemical Technology; Grayson, M., Exec. Ed.; Eckroth, D., Assoc. Ed.; John Wiley & Sons: New York, Chichester, Brisbane, Toronto, and Singapore, 1982; Vol. 17, pp 373–384.
60. Thurman, E. M.; Malcolm, R. L.; Aiken, G. R. Prediction of Capacity Factors for Aqueous Organic Solutes Adsorbed on a Porous Acrylic Resin. Anal. Chem. 1950, 50, 775–778.
61. Tóth, J. A Uniform Interpretation of Gas/Solid Adsorption. J. Colloid and Interface Sci. 1981, 79 (1), 85–95.
62. Van Vilet, B. M.; Weber, W. J., Jr. Comparative Performance of Synthetic Adsorbents and Activated Carbon for Specific Compound Removal from Wastewaters. J. Water Pollut. Control Fed. 1976, 48, 120.
63. Wang, S. W.; Hines, A. L.; Pedram, E. Extension of the Adsorption Potential Theory to Multi-Solute Adsorption of Aliphatic Acids from Dilute Aqueous Solution. Ind. Eng. Fundam. 1981, 20 (4), 350–355.
64. Weast, R. C., Ed. in chief; Astle, M. J., Beyer, W. H., Assoc. Eds. CRC Handbook of Chemistry and Physics, 66th ed.; CRC Press: Boca Raton, FL, 1985.
65. Weber, W. J., Jr.; van Vliet, B. M. Fundamental Concepts for Applications of Activated Carbon in Water and Wastewater Treatment. In Activated Carbon Adsorption of Organics in Water and Wastewater Treatment; Suffet, I. H., McGuire, M. J. Eds; Ann Arbor Science Publishers: Ann Arbor, MI, 1980; Vol. I, Chapter 1, pp 15–41.
66. Weber, W. J., Jr.; van Vliet, B. M. Synthetic Adsorbents and Activated Carbons for Water Treatment: Statistical Analyses and Interpretations. J. Am. Water Works Assoc. 1981a, 73 (8), 426–431.
67. Weber, W. J., Jr.; van Vliet, B. M. Synthetic Adsorbents and Activated Carbons for Water Treatment: Overview and Experimental Comparisons. J. Am. Water Works Assoc. 1981b, 73 (8), 420–426.
68. Williams, A. E. Benzoic Acid. In Kirk-Othmer Encyclopedia of Chemical Technology; Grayson, M., Exec. Ed.; Eckroth, D., Assoc. Ed.; John Wiley & Sons: New York, Chichester, Brisbane, Toronto, and Singapore, 1978; Vol. 3, pp 778–792.