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Note: It has been shown that GPC is not a useful tool for the determination of absolute molecular weights of rigid polymers. However, it is the only molecular weight characterization technique that gives information (and it is a valid tool in this respect for polyisocyanates) on the relative distribution of molecular weights within a polymer sample. Since K and α have not been determined for the polymers discussed in this paper (except poly(n-hexyl isocyanate)), we must rely on GPC for molecular weight information with the caveat that MWs and PDIs are higher than the true values. See
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Note: It has been shown that GPC is not a useful tool for the determination of absolute molecular weights of rigid polymers. However, it is the only molecular weight characterization technique that gives information (and it is a valid tool in this respect for polyisocyanates) on the relative distribution of molecular weights within a polymer sample. Since K and α have not been determined for the polymers discussed in this paper (except poly(n-hexyl isocyanate)), we must rely on GPC for molecular weight information with the caveat that MWs and PDIs are higher than the true values. See: Dubin, P. L.; Principi, J. M. Macromolecules 1989, 22, 1891.
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