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Volumn 34, Issue 39, 1993, Pages 6285-6288

Synthetic studies on polypropionate antibiotics based on the stereospecific methylation of γ δ-epoxy acrylates by trimethylaluminum. A highly stereoselective construction of the eight contiguous chiral centers of ansa-chains of rifamycins

Author keywords

[No Author keywords available]

Indexed keywords

RIFAMYCIN DERIVATIVE;

EID: 0027376631     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(00)73733-6     Document Type: Article
Times cited : (28)

References (25)
  • 21
    • 0001855559 scopus 로고
    • Synthesis of the Prelog-Djerassi Lactone and Protomycinolide IV Based on the Stereospecific Methylation of .GAMMA.,.DELTA.-Epoxy Acrylates by Trimethylaluminum.
    • Applications of the method to the synthesis of the Prelog-Djerassi lactone and Protomycinolide IV has been reported.
    • (1992) Chemistry Letters , pp. 1101
    • Miyashita1    Hoshino2    Yoshikoshi3    Kawamine4    Yoshihara5    Irie6
  • 22
    • 84918715311 scopus 로고    scopus 로고
    • The corresponding (E)-unsaturated ester was accompanied in 11% yield.
  • 23
    • 84918720388 scopus 로고    scopus 로고
    • 1H-NMR (400 or 500 MHz) spectrum.
  • 24
    • 84918761345 scopus 로고    scopus 로고
    • Stereochemistry of the epoxide was unequivocally established by comparison with the authentic epoxide prepared from the allylic alcohol by the Katsuki-Sharpless asymmetric epoxidation using D-(−)- or L-(+)-tartrate.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.