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Volumn 49, Issue 39, 1993, Pages 8787-8794

Reactivity of carbon nucleophiles with disubstituted tricarbonyl(pentadienyl)iron(1+) cations: Application to the synthesis of lasiol and epi-lasiol

Author keywords

(Pentadienyl)Fe(CO)3 cations; CC bond formation; terpene synthesis

Indexed keywords

LASIOL; TERPENE; UNCLASSIFIED DRUG;

EID: 0027364162     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(01)81900-1     Document Type: Article
Times cited : (29)

References (33)
  • 17
    • 0000729280 scopus 로고
    • The synthesis and reactivity of (4-heterosubstituted-1methylpentadienyl)iron cations has been reported:
    • (1992) J. Organomet. Chem. , vol.441 , pp. 449-456
    • Donaldson1    Bell2    Jin3
  • 19
    • 84918195693 scopus 로고    scopus 로고
    • All compounds are racemic mixtures of enantiomers. Only one enantiomer has been diagrammed for clarity.
  • 26
    • 84870397243 scopus 로고
    • Transition-metal mediated asymmetric synthesis. IV. Chelation of malonate esters by a chiral lanthanide shift reagent: a general method to measure theenantiomeric excess of tricarbonyl(cyclohexadienyl)iron(1+) salts
    • 3(1+) (i), which has a substituent pattern similar to 3b, reacts with malonate anion via attack only at the less substituted dienyl terminus:, [[Comment]]
    • (1982) Australian Journal of Chemistry , vol.35 , pp. 1939-1943
    • Stephenson1
  • 28
    • 84918195691 scopus 로고    scopus 로고
    • TM, Serena Software) has an Ar-Cl dihedral angle of 65°, while the lowest energy conformer of 1b has an Ar-Cl dihedral angle of 21°.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.