Strategies and tactics for free radical carbocyclization: synthesis of polyfunctionalized cyclopentanoid molecules from carbohydrates

Tetrahedron

Volumn 49, Issue 30, 1993, Pages 6669-6694

  Marco Contelles, José ^a   Ruiz, Pilar ^a   Martínez, Luis ^a   Martínez Grau, Angeles ^a  

^a INSTITUTO DE QUÍMICA ORGÁNICA GENERAL   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

CARBOHYDRATE; CYCLOPENTANE DERIVATIVE; FREE RADICAL;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; NUCLEAR MAGNETIC RESONANCE; STEREOSPECIFICITY; SYNTHESIS;

EID: 0027218926     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(01)81837-8     Document Type: Article

References (56)

1. New syntheses of carbocycles from carbohydrates. Cyclization of radicals derived from unsaturated halo sugars
2. Nonpeptide mimetics of .beta.-turns: a facile oxidative intramolecular cycloaddition of an azodicarbonyl system
3. Synthesis of Annulated Furanoses via Stereoselective Radical Cyclization of Haloalkenes Derived from Diacetone Glucose
4. Iridoids. A Review
5. Electron spin resonance spectroscopic investigation of carbohydrate radicals. Part 3. Conformation in deoxypyranosan-2-, -3-, and -4-yl radicals
6. Cyclopentane-annelated pyranosides: a new approach to chiral iridoid synthesis
7. Intramolecular radical cyclizations of 2-deoxy-2-iodohexopyranoside derivatives: routes to densely functionalized carbocycles
8. Novel reagent system for converting a hydroxy-group into an iodo-group in carbohydrates with inversion of configuration. Part 2
9. A New and Efficient Heterogeneous System for the Oxidative Cleavage of 1,2-Diols and the Oxidation of Hydroquinones
10. Stereospecific chain-branching by c-alkylation at the ketonic and enolic positions of 1,6-anhydro-2,3-o-isopropylidene-β-D-lyxo-hexopyranos-4-ulose
11. From carbohydrates to carbocycles. 2. A free radical route to Corey lactone and other prostanoid intermediates
12. A new synthetic route to .ALPHA.-methylene and .BETA.-methylene-.GAMMA.-butyrolactones via homolytic carbocyclization.
13. Acyl radical cyclizations in synthesis. Part 4. Tandem processes: the 7-endo/5-exo serial cyclization approach to enantiomerically pure bicyclo[5.3.0]decan-2-ones
14. Some guidelines for radical reactions
15. Rotational Isomerism Aboutsp2-sp3 Carbon-Carbon Single Bonds
16. The ?off-template? problem: towards a general solution
17. Synthesis of carbocyclic nucleosides: preparation of (?)-5?-homoaristeromycin and analogues
18. THE PREPARATION OF SOME DERIVATIVES OFD-RIBONO-1→4-LACTONE ANDD-RIBITOL
19. Rapid chromatographic technique for preparative separations with moderate resolution