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Volumn 34, Issue 28, 1993, Pages 4523-4526

Phosphine-borane complexes; direct use in asymmetric catalysis

Author keywords

[No Author keywords available]

Indexed keywords

ORGANOPHOSPHORUS COMPOUND; PHOSPHINE DERIVATIVE;

EID: 0027180004     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4039(93)88075-T     Document Type: Article
Times cited : (148)

References (14)
  • 11
    • 84914388511 scopus 로고    scopus 로고
    • P-C = 10.9 Hz) ; 109.2 (Cq) ; 128.4 – 132.6 (C aromatics).
  • 12
    • 84914388510 scopus 로고    scopus 로고
    • To a magnetically stirred suspension of the triphenylphosphine-borane complex (0,02 mol) in dry tetrahydrofuran (15 ml) at 25 °C were added thin, finely cut strips of lithium (0,04 mol). The mixture was stirred for 4 h during which time the colourless suspension turned into a red solution, and the lithium was consumed. Tert-butyl chloride (0,02 mol) was then added dropwise to the reaction and the solution was stirred for 30 min at 25 °C.
  • 14


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.