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Tetrahedron Letters

Volumn 33, Issue 41, 1992, Pages 6085-6088

Ion pair binding by a urea in chloroform solution.

(3) Smith, Paul J a Reddington, Mark V a Wilcox, Craig S a

a UNIVERSITY OF PITTSBURGH (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ANION; SULFONIC ACID DERIVATIVE; UREA DERIVATIVE;

ARTICLE; CATALYSIS; CHEMICAL REACTION; COMPLEX FORMATION; NUCLEAR MAGNETIC RESONANCE; PRIORITY JOURNAL; SPECTROPHOTOMETRY;

EID: 0026670457 PISSN: 00404039 EISSN: None Source Type: Journal
DOI: 10.1016/S0040-4039(00)60012-6 Document Type: Article

Times cited : (167)

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- Differences between thioureas and ureas in binding of guests have also been observed by A. Hamilton and E. Fan and by D. Curran and L.-H. Kuo of this Department. Joint experiments to explore quantitative aspects of this phenomenon are underway.

7
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8
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- Spectroscopic grade chloroform was used without further purification. The supplier specifies the solvent to contain 0.75% ethyl alcohol and 1–2 mM water. For a discussion of the effects of water and hydroxylic cosolvents on hydrogen bond based molecular recognition, see
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- −1) just as effectively as it binds to ion pairs 1–4.

13
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- 12b

14
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- This band-shift phenomenon, which was observed in none of our experiments, has been explained in terms of sequential replacement of solvent molecules by ions or ion pairs in the first solvation shell of the absorbing solute:
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- Transmission of polar effects. Part 18. Ionisation and esterification with diazodiphenylmethane of a series of 3-(8-substituted-1-naphthyl)propiolic and (E)-3-(8-substituted-1-naphthyl)acrylic acids and the alkaline hydrolysis of the methyl esters of the former series
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.