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Volumn 48, Issue 13, 1992, Pages 2681-2690

Copper catalysed preparation of vinyl ethers from unactivated vinylic halides

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE DERIVATIVE; CYCLOALKENE; ETHER DERIVATIVE; STYRENE DERIVATIVE;

EID: 0026561948     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(01)88528-8     Document Type: Article
Times cited : (24)

References (45)
  • 21
    • 84918236002 scopus 로고    scopus 로고
    • Keegstra, M.A.; Peters, T.H.A.; Brandsma, L. to be published.
  • 28
    • 84918236001 scopus 로고    scopus 로고
    • In the schemes and equations the catalytic intermediate is depicted as copper methoxide. This according to the proposal of Whitesides et al.: ref. 11.
  • 31
    • 0345329013 scopus 로고
    • Also compare the mechanisms in aromatic nucleophilic substitutions:
    • (1984) Tetrahedron , vol.40 , pp. 1433
    • Lindley1
  • 32
    • 0001559708 scopus 로고
    • Mechanisms and models for homogeneous copper mediated ligand exchange reactions of the type: CuNu + ArX → ArNu + CuX
    • (1985) Canadian Journal of Chemistry , vol.63 , pp. 111
    • Couture1    Paine2
  • 34
    • 84918236000 scopus 로고    scopus 로고
    • contrary to what was noted by Commercon et al. (ref. 9)
  • 35
    • 84918235999 scopus 로고    scopus 로고
    • In the case of a copper(III) intermediate the reaction has to occur in a solvent-cage. Otherwise the intermediate would easily be reduced, since Aalten et al. showed that even copper(II) was reduced to copper(I) in the presence of a concentrated solution of sodium methoxide: ref. 12a.
  • 41
  • 44
    • 84918235998 scopus 로고    scopus 로고
    • purchased at Janssen Chimica, the Netherlands.
  • 45
    • 84918235997 scopus 로고    scopus 로고
    • in the case of volatile products such as 1-methoxy-2-methylpropene Shell Sol T was used as the extraction solvent.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.