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Volumn 32, Issue 51, 1991, Pages 7567-7570

Enantioselective synthesis of (+)-magydardienediol

Author keywords

(+) magydardienediol; (+) magydartrienol.; asymmetric synthesis; diastereoselective synthesis; diterpene

Indexed keywords

DITERPENE; MAGYDARDIENEDIOL; UNCLASSIFIED DRUG;

EID: 0026331976     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4039(91)80536-F     Document Type: Article
Times cited : (7)

References (18)
  • 9
    • 0001782667 scopus 로고
    • Palladium-catalyzed allylation of ketones and aldehydes with allylic carbonates via silyl enol ethers under neutral conditions.
    • (1983) Chemistry Letters , pp. 1325
    • Tsuji1    Minami2    Shimizu3
  • 13
    • 84918603857 scopus 로고    scopus 로고
    • In this alkylation step, use of prenyl bromide instead of iodide or use of 1,2-dimethoxyethane as a solvent caused the contamination of (+)-4a with regioisomer [prenylation at C(6)].
  • 15
    • 84918612750 scopus 로고    scopus 로고
    • 3): δ=0.98(3H, s), 1.2–1.52(3H, m), 1.60(6H, s), 1.68(6H, s), 1.77–2.14(2H, m), 2.28(4H, m), 5.10(2H, m) 5.96, 1H, dt, [[Truncated]]
  • 16
    • 84918653430 scopus 로고    scopus 로고
    • 2 (J= 13 and 6 Hz). (3) The cis relationship of C(2)-H and C(6)-H was ascertained from the NOE enhancement.
  • 17


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.