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Volumn 251, Issue 4996, 1991, Pages 905-914

Polymer brushes

Author keywords

[No Author keywords available]

Indexed keywords

EQUATIONS OF STATE; MOLECULAR PHYSICS;

EID: 0026109156     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.251.4996.905     Document Type: Article
Times cited : (1796)

References (94)
  • 1
    • 0026107359 scopus 로고
    • F. Bates, Science 251, 898 (1991).
    • (1991) Science , vol.251 , pp. 898
    • Bates, F.1
  • 4
    • 0343510028 scopus 로고
    • _, Macromolecules 13, 1069 (1980).
    • (1980) Macromolecules , vol.13 , pp. 1069
  • 5
    • 0003411482 scopus 로고
    • Cornell Univ. Press, Ithaca, NY, chap. 14
    • Originally used to estimate the radius of a polymer coil swollen by solvent. See P. Flory, Principles of Polymer Chemistry (Cornell Univ. Press, Ithaca, NY, 1981), chap. 14; see also P.-G. de Gennes, Scaling Concepts in Polymer Physics (Cornell Univ. Press, Ithaca, NY, 1979), chap. 1.
    • (1981) Principles of Polymer Chemistry
    • Flory, P.1
  • 6
    • 0003544037 scopus 로고
    • Cornell Univ. Press, Ithaca, NY, chap. 1
    • Originally used to estimate the radius of a polymer coil swollen by solvent. See P. Flory, Principles of Polymer Chemistry (Cornell Univ. Press, Ithaca, NY, 1981), chap. 14; see also P.-G. de Gennes, Scaling Concepts in Polymer Physics (Cornell Univ. Press, Ithaca, NY, 1979), chap. 1.
    • (1979) Scaling Concepts in Polymer Physics
    • De Gennes, P.-G.1
  • 7
    • 85034896532 scopus 로고    scopus 로고
    • note
    • For ease of presentation, no mention will be made in this article of the effect of a chain avoiding itself. [The treatment in (2) emphasizes self-avoidance and gives its scaling description of brushes in terms of "blobs."] This omission is justified for moderately high coverage in brushes with not-too-good solvents (or for brushes without solvent); see (7). Except for altered exponents, the qualitative features of brushes (for instance, a "parabolic" profile for solvent brushes) are unaffected by self-avoidance; see (8).
  • 8
    • 0010264384 scopus 로고
    • S. F. Edwards, Proc. Phys. Soc. London 93, 605 (1965); see also P.-G. de Gennes, Scaling Concepts in Polymer Physics (Cornell Univ. Press, Ithaca, NY, 1979), section 6.2.1.
    • (1965) Proc. Phys. Soc. London , vol.93 , pp. 605
    • Edwards, S.F.1
  • 9
    • 0003544037 scopus 로고
    • Cornell Univ. Press, Ithaca, NY, section 6.2.1
    • S. F. Edwards, Proc. Phys. Soc. London 93, 605 (1965); see also P.-G. de Gennes, Scaling Concepts in Polymer Physics (Cornell Univ. Press, Ithaca, NY, 1979), section 6.2.1.
    • (1979) Scaling Concepts in Polymer Physics
    • De Gennes, P.-G.1
  • 11
    • 0024057280 scopus 로고
    • S. T. Milner, T. A. Witten, M. E. Gates, Europhys. Lett. 5, 413 (1988); Macromolecules 21, 2610 (1988).
    • (1988) Macromolecules , vol.21 , pp. 2610
  • 17
    • 0024663034 scopus 로고
    • A. Halperin and S. Alexander, Europhys. Lett. 6, 329 (1988); Macromolecules 22, 2403 (1989).
    • (1989) Macromolecules , vol.22 , pp. 2403
  • 25
    • 85034889921 scopus 로고    scopus 로고
    • note
    • It is tacitly assumed in (4), but not in (2), that the density profile is indeed flat.
  • 27
    • 33751026491 scopus 로고
    • J. M. H. M. Scheutjens and G. J. Fleer, J. Phys. Chem. 83, 1619 (1979); for a review, see G. J. Fleer, Colloids Surf. 35, 151 (1989). See also O. A. Evers, J. M. H. M. Scheutjens, G. J. Fleer, J. Chem. Soc. Faraday Trans. 86, 1333 (1990).
    • (1979) J. Phys. Chem. , vol.83 , pp. 1619
    • Scheutjens, J.M.H.M.1    Fleer, G.J.2
  • 28
    • 0024665789 scopus 로고
    • J. M. H. M. Scheutjens and G. J. Fleer, J. Phys. Chem. 83, 1619 (1979); for a review, see G. J. Fleer, Colloids Surf. 35, 151 (1989). See also O. A. Evers, J. M. H. M. Scheutjens, G. J. Fleer, J. Chem. Soc. Faraday Trans. 86, 1333 (1990).
    • (1989) Colloids Surf. , vol.35 , pp. 151
    • Fleer, G.J.1
  • 32
    • 0024753841 scopus 로고
    • M. Murat and G. S. Grest, Phys. Rev. Lett. 63, 1074 (1989); Macromolecules 22, 4054 (1989).
    • (1989) Macromolecules , vol.22 , pp. 4054
  • 39
    • 0025462320 scopus 로고
    • E. B. Zhulina, O. V. Borisov, V. A. Priamitsyn, J. Colloid Interface Sci. 137, 495 (1990); Vysokomol. Soedin. Ser. A 31, 185 (1989).
    • (1989) Vysokomol. Soedin. Ser. A , vol.31 , pp. 185
  • 43
    • 0025414626 scopus 로고
    • M. R. Munch and A. P. Gast, Macromolecules 23, 2313 (1990); J. Chem. Soc. Faraday Trans. 86, 1341 (1990).
    • (1990) Macromolecules , vol.23 , pp. 2313
    • Munch, M.R.1    Gast, A.P.2
  • 44
    • 0000110606 scopus 로고
    • M. R. Munch and A. P. Gast, Macromolecules 23, 2313 (1990); J. Chem. Soc. Faraday Trans. 86, 1341 (1990).
    • (1990) J. Chem. Soc. Faraday Trans. , vol.86 , pp. 1341
  • 58
    • 0025249415 scopus 로고
    • _, Macromolecules 23, 571 (1990).
    • (1990) Macromolecules , vol.23 , pp. 571
  • 62
    • 0025227754 scopus 로고
    • H. W. Hu, J. Van Akten, S. Granick, Langmuir 5, 270 (1989); H. W. Hu and S. Granick, Macromolecules 23, 613 (1990).
    • (1990) Macromolecules , vol.23 , pp. 613
    • Hu, H.W.1    Granick, S.2
  • 68
    • 85034893139 scopus 로고    scopus 로고
    • private communication
    • J. Israelachvili, private communication.
    • Israelachvili, J.1
  • 70
    • 36749110355 scopus 로고
    • K. Freed and S. F. Edwards, J. Chem. Phys. 61, 3626 (1974); see also P.-G. de Gennes, Macromolecules 9, 594 (1976).
    • (1974) J. Chem. Phys. , vol.61 , pp. 3626
    • Freed, K.1    Edwards, S.F.2
  • 71
    • 0346316563 scopus 로고
    • K. Freed and S. F. Edwards, J. Chem. Phys. 61, 3626 (1974); see also P.-G. de Gennes, Macromolecules 9, 594 (1976).
    • (1976) Macromolecules , vol.9 , pp. 594
    • De Gennes, P.-G.1
  • 73
    • 0025413746 scopus 로고
    • F. D. Blum, B. R. Sinha, F. C. Schwab, Macromolecules 23, 3592 (1990); for a review, see F. D. Blum, Colloids Surf. 45, 361 (1990).
    • (1990) Colloids Surf. , vol.45 , pp. 361
    • Blum, F.D.1
  • 76
    • 0000186637 scopus 로고
    • A. K. Dolan and S. F. Edwards, Proc. R. Soc. London Ser. A 337, 509 (1974); ibid. 343, 427 (1975).
    • (1975) Proc. R. Soc. London Ser. A , vol.343 , pp. 427
  • 80
    • 33847799791 scopus 로고
    • This article does not discuss numerical solutions of the mean-field equations by expansion in eigenfunctions, developed by E. Helfand and Z. R. Wasserman [Macromolecules 9, 879 (1976); ibid. 11, 960 (1978)]. For recent applications to brushes, see (24) and M. D. Whitmore and J. Noolandi, ibid. 21, 1482 (1988).
    • (1976) Macromolecules , vol.9 , pp. 879
    • Helfand, E.1    Wasserman, Z.R.2
  • 81
    • 0345251822 scopus 로고
    • This article does not discuss numerical solutions of the mean-field equations by expansion in eigenfunctions, developed by E. Helfand and Z. R. Wasserman [Macromolecules 9, 879 (1976); ibid. 11, 960 (1978)]. For recent applications to brushes, see (24) and M. D. Whitmore and J. Noolandi, ibid. 21, 1482 (1988).
    • (1978) Macromolecules , vol.11 , pp. 960
  • 82
    • 0024012293 scopus 로고
    • This article does not discuss numerical solutions of the mean-field equations by expansion in eigenfunctions, developed by E. Helfand and Z. R. Wasserman [Macromolecules 9, 879 (1976); ibid. 11, 960 (1978)]. For recent applications to brushes, see (24) and M. D. Whitmore and J. Noolandi, ibid. 21, 1482 (1988).
    • (1988) Macromolecules , vol.21 , pp. 1482
    • Whitmore, M.D.1    Noolandi, J.2
  • 84
    • 85034897018 scopus 로고
    • thesis, University of Minnesota, Minneapolis
    • S. Hirz, thesis, University of Minnesota, Minneapolis (1986).
    • (1986)
    • Hirz, S.1
  • 90
    • 0025465163 scopus 로고
    • T. M. Birshtein and E. B. Zhulina, Polymer 30, 170 (1989); ibid. 31, 1312 (1990).
    • (1990) Polymer , vol.31 , pp. 1312
  • 94
    • 85034888920 scopus 로고    scopus 로고
    • note
    • It is a pleasure to acknowledge my collaboration with Tom Witten and Michael Cates and helpful conversations with many of the authors represented in this article.


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