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Volumn 32, Issue 15, 1991, Pages 1831-1834

Controlling the reactivity of permanganate anion. Novel, stereospecific, dichlorination of olefins

Author keywords

[No Author keywords available]

Indexed keywords

ORGANOCHLORINE DERIVATIVE;

ARTICLE; PRIORITY JOURNAL; REACTION ANALYSIS; SYNTHESIS;

EID: 0026071213 PISSN: 00404039 EISSN: None Source Type: Journal
DOI: 10.1016/S0040-4039(00)74342-5 Document Type: Article

Times cited : (25)

References (10)

1
- 0003757056
- K.B. Wiberg, Acad. Press, NY, Part A
- (1965) Oxidations in Organic Chemistry , pp. 1
- Stewart¹

2
- 0002626037
- W.S. Trahanovsky, Acad. Press, NY
- (1982) Oxidation in Organic Chemistry , vol.5-500 , pp. 147
- Lee¹

4
- 84982370424
- Transannular course in the addition of halogen to cis-cyclo-octene and in some related reactions
- The formation of cis vicinal dichlorides by other organometallic reagents has been reported
- (1966) Recueil des Travaux Chimiques des Pays-Bas , vol.85 , pp. 1177
- Henniger¹ Dukker² Havinga³

5
- 2542626593
- -generated molybdenum (VI) reagent for -chlorination of alkenes
- (1978) Tetrahedron Letters , pp. 3427
- Nugent¹

7
- 0001785268
- For an example of trans dichlorination, see
- (1989) J. Chem. Res (S) , pp. 108
- Bellesia¹ Ghelfi² Pagnoni³ Pinetti⁴

8
- 84918630172
- The only exception we have encountered so far is trans - stilbene which gives a mixture of d, l and meso dichlorides (1 : 1).

9
- 84918631402
- This observation also rules out the formation and participation of chlorine as the dichlorinating agent. It is also worth noting that, under the same conditions, chlorination using molecular chlorine does not proceed to any appreciable extend.

10
- 0000177827
- For an initial modification of permanganate reactivity using acetic anhydride, see
- (1971) J. Am. Chem. Soc. , vol.93 , pp. 3303
- Sharpless¹ Lauer² Repic³ Teranishi⁴ Williams⁵

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