Epoxy-epimination of cyclic conjugated dienes-VII-. Cycloaddition of nitroso-halogenobenzenes to cyclopentadiene followed by rearrangement to epoxy-epimino- and γ-δ-epimino-pentadienal derivatives via NO and CC bond breaking.

Tetrahedron

Volumn 47, Issue 39, 1991, Pages 8323-8330

  Rousselle, Daniel ^a   Francotte, Eric ^a   Feneau Dupont, Jeannine ^a   Tinant, Bernard ^a   Declercq, Jean P ^a   Viehe, Heinz G ^a  

^a UNIVERSITÉ CATHOLIQUE DE LOUVAIN   (Belgium)

Author keywords

Aziridination Ariridinopentadienal Epoxy epimine Hetero Diels Alder Rearrangement

Indexed keywords

IMINE;

ARTICLE; CHEMICAL STRUCTURE; NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; SYNTHESIS; X RAY ANALYSIS;

EID: 0025998222     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(01)96173-3     Document Type: Article

References (23)

1. Photochemical rearrangement of diene endoperoxides
2. Nitrosoalkenes: Synthesis and Reactivity
3. N-(Dichloro-2,2 vinyl) épimino-1,2 époxy-4,5 cyclopentadiène
4. A New Peroxide Rearrangement:cis-4,5-Epoxy-2-pentenal from 1,4-Epidioxy-2-cyclopentene