Cooperation in a deep helical energy well

Chirality

Volumn 3, Issue 4, 1991, Pages 285-291

  Green, Mark M ^a   Lifson, Shneior ^b   Teramoto, Akio ^c  

^a POLYTECHNIC UNIVERSITY   (United States)

^b WEIZMANN INSTITUTE OF SCIENCE   (Israel)

^c OSAKA UNIVERSITY   (Japan)

Author keywords

deuterium; macromolecular; optical activity; polyisocyanate

Indexed keywords

POLYMER;

ARTICLE; CHEMICAL STRUCTURE; CIRCULAR DICHROISM;

EID: 0025939224     PISSN: 08990042     EISSN: 1520636X     Source Type: Journal    
DOI: 10.1002/chir.530030412     Document Type: Article

References (34)

1. The homopolymerization of monoisocyanates
2. The chain structure, polymerization and conformation of polyisocyanates
3. Solvent dependence of the chain dimension of poly(n‐hexyl isocyanate)
4. Dielectric dispersion of narrow distribution poly(hexyl isocyanate) in dilute solution
5. Structure of poly(n‐butyl isocyanate)
6. Conformational characteristics of the poly(n‐alkyl isocyanates)
7. Broken wormlike chain model of semiflexible polymers
8. Flexibility in rigid rod poly(n‐alkyl isocyanates)
9. The stereochemistry of linear macromolecules
10. The control of main chain conformation in vinyl and related polymers
11. The unperturbed dimensions of poly‐(S)‐4‐methyl‐1‐hexene and poly‐4‐methyl‐1‐pentene
12. Optically active polyisocyanates
13. Macromolecular Stereochemistry: The effect of pendant group structure on the axial dimension of polyisocyanates
14. Broken worm and wormlike models for polyisocyanates
15. Macromolecular stereochemistry: a cooperative deuterium isotope effect leading to a large optical rotation
16. Macromolecular stereochemistry: Helical Sense Preference in Optically Active Polyisocyanates. Amplification of a Conformational Equilibrium Deuterium Isotope Effect
17. Conformational Properties of optically active poly‐α‐olefines in solution
18. A model of the chain conformation of an isotactic vinyl polymer, having optically active side groups
19. Optical activity and conformation in solution of stereoregular copolymers of (S)‐4‐methyl‐1‐hexane with 4‐methyl‐1‐pentene
20. Macromolecular stereochemistry: The out‐of‐proportion influence of optically active comonomers on the conformational characteristics of polyisocyanates. The sergeants and soldiers experiment
21. Wormlike chain parameters of poly(hexyl isocyanate) in dilute solution
22. Deuterium isotope effects on the ring inversion equilibrium in cyclohexane: A value of deuterium and its origin
23. Conformationally dependent intrinsic and equilibrium isotope effects in N‐methylpiperidine
24. Some future aspects of stereochemistry
25. What will chemistry do in the next twenty years
26. Cooperation
27. Fluorescence study of the complexation of poly(acrylic acid) with poly (N, N‐dimethylacrylamide‐coacrylamide)
28. Phase diagrams of poly(vinylmethyl ether)—deuterated polystyrene: An original route to the precise nature of polymer‐polymer interactions
29. Hydration forces between phospholipid bilayers
30. Liquid crystals: A tool for studies on chirality
31. Solvent effects on the cooperative order‐disorder transition of aqueous solutions of schizophyllan, a triple‐helical polysaccharide
32. Crystalline polymers of phenyl and n‐butylisocyanate