Thermal rearrangement of N-silymethylated azadienes to N-silylated 2-pyrrolines

Tetrahedron Letters

Volumn 32, Issue 38, 1991, Pages 5093-5096

  Ohno, Mitsuru ^a   Miyata, Hiroyuki ^a   Komatsu, Mitsuo ^a   Ohshiro, Yoshiki ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

AZIRIDINE DERIVATIVE; PYRROLE DERIVATIVE;

ARTICLE; PRIORITY JOURNAL; REACTION ANALYSIS; SYNTHESIS;

EID: 0025863449     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(00)93436-1     Document Type: Article

References (14)

1. Stereospecific synthesis of retronecine by imidate methylide cycloaddition
2. 1,3-Dipolar cycloaddition leading to N-acylated pyrrolidines and 2,5-dihydropyrroles.
3. An expedient synthetic approach to the physostigmine alkaloids via intramolecular formamidine ylide cycloadditions
4. New C-C bond formation with pyridinium methylide: Hydromethylenation of olefin.
5. N-(Trimethylsilylmethyl)aminomethyl ethers as azomethine ylide synthons. A new and convenient access to pyrrolidine derivatives.
6. Synthetic versatility of N-(silylmethyl)imines : Water-induced generation of N-protonated azomethine ylides of nonstabilized type and fluoride-induced generation of 2-azaallyl anions.
7. Stereoselective synthesis of cis-2,3-diarylaziridine by rearrangement of aryl-substituted N-(silylmethyl)imine.
8. Stereoselectivity of cycloaddition of N-(cyanomethyl)- and N-(.ALPHA.-cyanobenzyl)imines with olefinic dipolarophiles. Synthetic equivalents of nitrile ylide 1,3-dipoles.
9. Benzylidene(cyano)benzylamine as a 1,3-Dipole