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Volumn 32, Issue 30, 1991, Pages 3683-3686

Acyclic diastereofacial selection in radical addition.

Author keywords

2 Asymmetric induction Stereoelectronic control.; Acyclic diastereofacial selection Intermolecular radical addition 1

Indexed keywords

1,3 DIOXOLANE DERIVATIVE;

EID: 0025766611     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(00)79767-X     Document Type: Article
Times cited : (27)

References (33)
  • 1
    • 0345678962 scopus 로고
    • Radical Cyclization of (Bromomethyl)dimethylsilyl Propargyl Ethers; VI. Serial Radical Cyclizations Leading to a Stereoselective Synthesis of Functionalized Diquinane Framework from an Acyclic Substrate1
    • Part VII. For part VI see:
    • (1990) Synlett , pp. 320
    • Journet1    Smadja2    Malacria3
  • 2
    • 84990135406 scopus 로고
    • The Stereoselectivity of Intermolecular Free Radical Reactions [New Synthetic Methods (78)]
    • An excellent review appeared recently dealing with stereoselectivity in intermolecular free radical reactions:
    • (1989) Angewandte Chemie International Edition in English , vol.28 , pp. 969-980
    • Giese1
  • 13
    • 85022849477 scopus 로고
    • Stereoselective Addition of Carbon-Centered Radicals to Chiral Enamines
    • (1990) Synlett , pp. 624
    • Renaud1    Schubert2
  • 16
    • 0006155346 scopus 로고
    • Z and E -chiral enoate 1 has already been used in various stereoselective reactions for cycloaddition see:
    • (1986) Tetrahedron Lett. , vol.27 , pp. 4137
    • Trost1    Mignani2
  • 25
    • 84914276117 scopus 로고    scopus 로고
    • 3SiH in thermal conditions, does not seem to occur, only some Z to E isomerization of ester Z -1 has been detected.
  • 26
    • 85034895022 scopus 로고
    • Hydrosilylation and Cyclization Reactions of Alkenes and Ketones with Tris(trimethylsilyl)silane
    • 3SiH see:
    • (1990) Synlett , pp. 91
    • Kulicke1    Giese2
  • 28
    • 84914276116 scopus 로고    scopus 로고
    • 3, 200 MHz): 7.60–7.69 (m, 4H, phenyl); 7.30–7.43 (m, 6H, phenyl); 4.86 ppm (m, SiH); 4.23 (m, 4H); 4.00, q, J=7.2 Hz, [[Truncated]]
  • 30
    • 84914276115 scopus 로고    scopus 로고
    • + which is quantitative with starting materials Z and E-1, affords complex mixtures with major and minor silylated adducts 2.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.